18620-18-3Relevant articles and documents
Reinvestigation of the fluoride-triggered condensation of allyltrimethylsilane with cinnamonitrile: 'Abnormal Sakurai' and sequential 'abnormal Sakurai'-Michael-Thorpe Ziegler side reactions
Keller, Laurent,Dumas, Fran?oise,Pizzonero, Mathieu,D'Angelo, Jean,Morgant, Georges,Nguyen-Huy, Dung
, p. 3225 - 3228 (2002)
Together with the expected 1,4-adduct, three by-products are generated in the fluoride-triggered condensation of allyltrimethylsilane with cinnamonitrile: the 1,3 adduct, an acyclic dinitrile and a cyclopentenaminonitrile issuing, respectively, from 'abnormal Sakurai', 'abnormal Sakurai'-Michael and 'abnormal Sakurai'-Michael-Thorpe Ziegler side reactions.
Rearrangements of substituted 3-aza-1,2,5-hexatrienes. 3. The scope and versatility of an extremely mild 3-aza-Cope reaction
Walters, Michael A.,Hoem, Andrew B.,McDonough, Colleen S.
, p. 55 - 62 (2007/10/03)
An investigation of the [3,3]-sigmatropic reaction of substituted 3-aza-1,2,5-hexatrienes to give 4-pentenenitriles is presented. This reaction has been found to occur under a wide variety of reactions conditions (10 are reported) starting from readily av
