186267-23-2Relevant academic research and scientific papers
Facile synthesis of metalla-octafluorocyclopentane complexes of ruthenium and nickel
Gasafi-Martin,Oberendfellner,von Werner
, p. 1922 - 1924 (1996)
Reduction of the dihalogeno complexes RuCl2(PPh3)4 and NiBr2L2 (L = tertiary phosphine) with sodium hydride in MeCN in the presence of tetrafluoroethylene gives complexes containing five-membered MC4F8 rings. 1,2-Dihydrotetrafluoroethane is a by-product of these syntheses, especially when hydrogen is added. The M - C bonds of the metalla-perfluorocyclopentane complexes are remarkably stable against hydrogenolysis.
