Facile synthesis of metalla-octafluorocyclopentane complexes of ruthenium and nickel

DOI: 10.1139/v96-217

Source and publish data:

Canadian Journal of Chemistry p. 1922 - 1924 (1996)

Update date:2022-08-03

Topics:

Authors:

Gasafi-Martin

Oberendfellner

von Werner

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Article abstract of DOI:10.1139/v96-217

Reduction of the dihalogeno complexes RuCl₂(PPh₃)₄ and NiBr₂L₂ (L = tertiary phosphine) with sodium hydride in MeCN in the presence of tetrafluoroethylene gives complexes containing five-membered MC₄F₈ rings. 1,2-Dihydrotetrafluoroethane is a by-product of these syntheses, especially when hydrogen is added. The M - C bonds of the metalla-perfluorocyclopentane complexes are remarkably stable against hydrogenolysis.

Full text of DOI:10.1139/v96-217

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