18636-66-3

Basic information

• Product Name: 1-Butoxypentane
• Synonyms: 1-Butoxypentane;Butylpentyl ether
• CAS NO: 18636-66-3
• Molecular Formula: C₉H₂₀O
• Molecular Weight: 144.2545
• Mol File: 18636-66-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 163.8°Cat760mmHg
• Flash Point: 43.7°C
• Appearance: /
• Density: 0.786g/cm³
• Vapor Pressure: 2.65mmHg at 25°C
• Refractive Index: 1.41
• CAS DataBase Reference: 1-Butoxypentane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butoxypentane(18636-66-3)
• EPA Substance Registry System: 1-Butoxypentane(18636-66-3)

Safety Data

• Hazardous Substances Data: 18636-66-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H20O/c1-3-5-7-9-10-8-6-4-2/h3-9H2,1-2H3

Upstream product

• 2465-56-7 methylene 
• 142-96-1 dibutyl ether 
• 109-72-8 n-butyllithium 
• 2351-69-1 1-(chloromethoxy)butane 
• 110-53-2 1-Bromopentane 
• 71-36-3 butan-1-ol 
• 543-59-9 1-Chloropentane 
• 34061-78-4 4-pentyloxy-but-1-ene 
• 109-69-3 n-Butyl chloride 
• 71-41-0 pentan-1-ol 
• 542-69-8 1-iodo-butane 
• 109-65-9 1-bromo-butane 
• 5867-98-1 dipentyl sulfate 
• 2372-45-4 sodium butanolate 

Relevant articles and documents

Cesium fluoride-Celite: A solid base for efficient syntheses of aromatic esters and ethers

Coupling reactions of a number of aromatic and heteroaromatic phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite are described, demonstrating that this reagent provides an efficient, convenient and practical method for the syntheses of aromatic esters and ethers.

Organomagnesium Inner Complexes, Part I. Bis(dialkylaminoalkyl)- and Bis(alkoxybutyl)magnesium Compounds

A series of magnesium inner complexes has been prepared by reacting MgH2 (prepared by homogeneous catalysis) with dialkylallyl- and -3-butenylamines and -3-butenylethers in the presence of catalytic amounts of ZrCl4.The monomeric nature of bis(4-methoxybutyl)magnesium has been confirmed by X-ray diffraction.The analogous syntheses of bis(3-alkoxypropyl)magnesium compounds failed: cleavage of the allyl ether with elimination of propene occurred.This cleavage reaction is accelerated by catalytic amounts of NiCl2 or ZrCl4. - Keywords: Magnesium, Inner Complexes, Crystal Structure, X-Ray

FLUORINATION OF 2-ALKYL-SUBSTITUTED OXIRANES. THE SYNTHESIS AND PURIFICATION OF PERFLUORO(2-ALKYL-SUBSTITUTED OXANE)S

Five kinds of 2-alkyl-substituted oxanes like 2-ethyloxane, 2-n-propyloxane, 2-iso-propyloxane, 2-n-butyloxane and 2-n-amyloxane were fluorinated electrochemically to give the corresponding perfluoro(2-alkyloxane)s.The perfluoro(2-alkyloxane)s were obtained in good yields from these starting materials together with isomeric perfluoro(2-alkyloxolane)s, perfluoro(2-alkyl-5-methyloxolane)s and perfluoro(dialkyl ether)s.The purification of the perfluoro(2-alkyloxane)s which contained small amounts of isomeric perfluoro(2-alkyloxolane)s was succesfully achieved by recovering the former unreacted after treating these mixtures with anhydrous aluminum chloride at 150-160 deg C during ca. 48 hrs in order to convert the latter into the easy-separable perfluoro-(2,5,5-trichloro-2-alkyloxolane)s.Small quantities of new perfluoro(5,5-dichloroalkanoyl chloride)s were also among the chlorination products.The spectroscopic data as well as the physical properties of these new fluorination products, and perfluoro(2,5,5-trichloro-2-alkyloxolane)s and perfluoro(5,5-dichloroalkanoyl chloride)s are presented.