186395-02-8

Basic information

• Product Name: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium
• Synonyms: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium
• CAS NO: 186395-02-8
• Molecular Weight: 825.021
• Mol File: 186395-02-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium(CAS DataBase Reference)
• NIST Chemistry Reference: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium(186395-02-8)
• EPA Substance Registry System: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium(186395-02-8)

Safety Data

• Hazardous Substances Data: 186395-02-8(Hazardous Substances Data)

Upstream product

• 189276-36-6 (2-iodophenyloxymethyl)trimethylsilane 
• 189276-41-3 ((C₆H₅)3As)2IPd(C₆H₄OCH₂Si(CH₃)2C₆H₅) 
• 189276-40-2 ((C₆H₅)3As)2IPd(C₆H₄OCH₂Si(CH₃)3) 
• 189276-42-4 ((C₆H₅)3As)2IPd(C₆H₄OCH₂Si(CH₃)2F) 
• 189276-40-2 trans-bis(triphenylarsine)iodo[2-(trimethylsilylmethoxy)phenyl]palladium 
• 189276-42-4 trans-bis(triphenylarsine)[2-(fluorodimethylsilylmethoxy)phenyl]iodopalladium 

Relevant articles and documents

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Through the combination of reaction kinetics (both catalytic and stoichiometric) and solid-state characterization of arylpalladium(II) alkenylsilanolate complexes, the intermediacy of covalent adducts containing Si-O-Pd linkages in the cross-coupling reac

Isolation of the transmetalation step in the hiyama cross-coupling reaction of organosilanes

The oxidative addition of o-(Me2RSiCH2O)C6H4I (R = Me, Ph, F) to palladium(0) complexes leads to the corresponding complexes o-(Me2RCH2O)C6H4Pd(L2)I (L = PP