bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium

Base Information

• Chemical Name: bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium
• CAS No.: 186395-02-8
• Molecular Formula: C₄₃H₃₆As₂OPd
• Molecular Weight: 825.021
• Mol file: 186395-02-8.mol

Synonyms:bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium

Chemical Property of bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium

There total 8 articles about bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trans-bis(triphenylarsine)iodo[2-(trimethylsilylmethoxy)phenyl]palladium (189276-40-2) → bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium (186395-02-8)

Guidance literature:

With potassium carbonate; In acetonitrile; Ar-atmosphere; 2 equivs. of K2CO3, 50°C, 5 h;

DOI:10.1021/om980157o

Reference yield: 100.0%

((C6H5)3As)2IPd(C6H4OCH2Si(CH3)2F) (189276-42-4) → bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium (186395-02-8)

Guidance literature:

With [(Me₂N)3S][F₂SiMe₃]; In acetonitrile; 23°C (1 h); detd. by (1)H NMR spectroscopy;

DOI:10.1021/om970085l

Reference yield: 100.0%

((C6H5)3As)2IPd(C6H4OCH2Si(CH3)3) (189276-40-2) → bis(triphenylarsine)(methyleneoxy-1,2-phenylene)palladium (186395-02-8)

Guidance literature:

With potassium carbonate; In acetonitrile; 50°C (5 h);

DOI:10.1021/om970085l

upstream raw materials:

trans-bis(triphenylarsine)[2-(fluorodimethylsilylmethoxy)phenyl]iodopalladium

trans-bis(triphenylarsine)iodo[2-(trimethylsilylmethoxy)phenyl]palladium

((C₆H₅)3As)2IPd(C₆H₄OCH₂Si(CH₃)2F)

((C₆H₅)3As)2IPd(C₆H₄OCH₂Si(CH₃)3)

Refernces

• 1、 Mateo, Cristina,Fernández-Rivas, Carolina,Cárdenas, Diego J.,Echavarren, Antonio M.. "Intramolecular transmetalation of arylpalladium(II) and arylplatinum(II) complexes with silanes and stannanes". . p. 3661 - 3669. Retrieved 2008/10/08.