18641-82-2Relevant academic research and scientific papers
SYNTHETIC APPLICATION OF MICELLAR CATALYSIS. WILLIAMSON'S SYNTHESIS OF ETHERS
Jursic, Branko
, p. 6677 - 6680 (2007/10/02)
A simple, rapid and efficient procedure for the preparation of di-alkyl, simple phenyl-alkyl and hindered phenyl-alkyl ethers has been developed.Based on the principle of micellar catalysis the method involves alkylation of the alkoxide or the phenoxide ion with an alkyl chloride at 80 deg C in the presence of cationic micelles.For the preparation of phenyl-alkyl ethers normal micelles were used, while for the di-alkyl ethers reverse micelles were more effective.By increasing the ionic strength of the solution the rate of formation of phenyl-alkyl ethers could be increased.
Low-energy, Low-temperature Mass Spectra. Part 3. n-Pentyl n-Alkyl Ethers
Bowen, D. Richard,Maccoll, Allan
, p. 1101 - 1104 (2007/10/02)
The 12.1 eV electron-impact-induced mass spectra of five homologous pentyl alkyl ethers (n-C5H11OR; R=CH3, C2H5, n-C3H7, n-C4H9, and n-C5H11) are reported.The trends in these spectra are discussed in energetic terms and compared with the spectrum of the p
