186451-82-1

Upstream product

• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 60068-02-2 2,6,6-Trimethyl-3-isobutoxycyclohex-2-en-1-one 
• 825614-90-2 3-allyl-2,4,4-trimethyl-2-cyclohexen-1-one 
• 825614-92-4 3-(2,3-dihydroxypropyl)-2,4,4-trimethyl-2-cyclohexen-1-one 

Downstream Products

• 83646-52-0 3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-ol 
• 75203-87-1 3-(2-hydroxyethyl)-2,4,4-trimethyl-2-cyclohexen-1-one 
• 825614-94-6 3-[2-(tert-butyldimethylsilyloxy)ethyl]-2,4,4-trimethyl-2-cyclohexen-1-one 
• 825614-95-7 3-[2-(tert-butyldimethylsilyloxy)ethyl]-6-hydroxy-2,4,4-trimethyl-2-cyclohexen-1-one 

Relevant academic research and scientific papers

Practical and efficient 1α-hydroxylation of 4,4-dimethyl-2-ene derivatives in terpenic series

The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO2-

First synthesis of (+/-)-robinlin.

The first synthesis of (+/-)-robinlin (1), a novel homo-monoterpene with strong bioactivity in the brine shrimp lethality test, was achieved by starting from 3-isobutyloxy-2,6,6-trimethyl-2-cyclohexen-1-one (2).