Practical and efficient 1α-hydroxylation of 4,4-dimethyl-2-ene derivatives in terpenic series

Article abstract of DOI:10.1080/00397919708004804

The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO₂-

Full text of DOI:10.1080/00397919708004804

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Practical and Efficient
1α-Hydroxylation of 4,4-
Dimethyl-2-Ene Derivatives
in Terpenic Series
Gérard Aranda a , Mireille Bertranne-Delahaye
a , Robert Azerad b , Michèle Maurs b , Manuel
Cortés c , Hector Ramirez c , Gonzalo Vernal c
Thierry Prangé d
a Laboratoire de Synthèse Organique , Associé
&
au CNRS, Ecole Polytechnique , Palaiseau Cedex,
91128, France
b Laboratoire de Chimie et Biochimie
Pharmacologiques et Toxicologiques , Université
René Descartes-Paris V , 45 Rue des Saints
Pères, Paris, 75006, France
c Pontificia Universidad Católica de Chile,
Facultad de Química , Casilla 306, Correo 22,
Santiago, Chile
d Chimie Structurale Biomoléculaire , URA 1430,
Rue M. Cachin, 93017, Bobigny Cedex, France
Published online: 19 Aug 2006.
To cite this article: Gérard Aranda , Mireille Bertranne-Delahaye , Robert
Azerad , Michèle Maurs , Manuel Cortés , Hector Ramirez , Gonzalo Vernal &
Thierry Prangé (1997) Practical and Efficient 1α-Hydroxylation of 4,4-Dimethyl-2-
Ene Derivatives in Terpenic Series, Synthetic Communications: An International

Journal for Rapid Communication of Synthetic Organic Chemistry, 27:1, 45-60,
DOI: 10.1080/00397919708004804
To link to this article: http://dx.doi.org/10.1080/00397919708004804
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