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cis-[Fe(CH=CHCOOMe)(dppe)2]BF4 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

186519-15-3

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186519-15-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 186519-15-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,6,5,1 and 9 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 186519-15:
(8*1)+(7*8)+(6*6)+(5*5)+(4*1)+(3*9)+(2*1)+(1*5)=163
163 % 10 = 3
So 186519-15-3 is a valid CAS Registry Number.

186519-15-3Downstream Products

186519-15-3Relevant academic research and scientific papers

Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an Fe-H bond: Crystal structure of cis-[Fe(CH=CHCOOMe)(Ph2PCH2CH2PPh2)2][BF4]

Almeida, Silvia S. P.,Duarte, Maria T.,Ribeiro, Luisa M. D.,Gormley, Fiona,Galvao, Adeline M.,Frausto Da Silva, Joao J. R.,Pombeiro, Armando J. L.

, p. 63 - 66 (1996)

Treatment of a THF solution of trans-[FeHCl(dppe)2] (dppe = Ph2PCH2CH2PPh2) with HC≡CCOOMe or CS2, in the presence of T1[BF4], forms the vinyl complex cis-[Fe(CH=CHCOOMe)(dppe)2][BF4] or the η2-dithioformate compound cis-[Fe(η2-S2CH)(dppe)2][BF4] respectively. The molecular structure of the former is authenticated by X-ray diffraction analysis.

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