Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an Fe-H bond: Crystal structure of cis-[Fe(CH=CHCOOMe)(Ph2PCH2CH2PPh2)2][BF4]

DOI: 10.1016/S0022-328X(96)06290-0

Source and publish data:

Journal of Organometallic Chemistry p. 63 - 66 (1996)

Update date:2022-08-02

Topics:

Authors:

Almeida, Silvia S. P.

Duarte, Maria T.

Ribeiro, Luisa M. D.

Gormley, Fiona

Galvao, Adeline M.

Frausto Da Silva, Joao J. R.

Pombeiro, Armando J. L.

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Article abstract of DOI:10.1016/S0022-328X(96)06290-0

Treatment of a THF solution of trans-[FeHCl(dppe)₂] (dppe = Ph₂PCH₂CH₂PPh₂) with HC≡CCOOMe or CS₂, in the presence of T1[BF₄], forms the vinyl complex cis-[Fe(CH=CHCOOMe)(dppe)₂][BF₄] or the η²-dithioformate compound cis-[Fe(η²-S₂CH)(dppe)₂][BF₄] respectively. The molecular structure of the former is authenticated by X-ray diffraction analysis.

Full text of DOI:10.1016/S0022-328X(96)06290-0

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