Formation of vinyl and dithioformate metallacycles by insertion of an ester-functionalized alkyne or carbon disulfide into an Fe-H bond: Crystal structure of cis-[Fe(CH=CHCOOMe)(Ph2PCH2CH2PPh2)2][BF4]

DOI: 10.1016/S0022-328X(96)06290-0

Source and publish data:

Journal of Organometallic Chemistry p. 63 - 66 (1996)

Update date:2022-08-02

Topics:

Authors:

Almeida, Silvia S. P.

Duarte, Maria T.

Ribeiro, Luisa M. D.

Gormley, Fiona

Galvao, Adeline M.

Frausto Da Silva, Joao J. R.

Pombeiro, Armando J. L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(96)06290-0

Treatment of a THF solution of trans-[FeHCl(dppe)₂] (dppe = Ph₂PCH₂CH₂PPh₂) with HC≡CCOOMe or CS₂, in the presence of T1[BF₄], forms the vinyl complex cis-[Fe(CH=CHCOOMe)(dppe)₂][BF₄] or the η²-dithioformate compound cis-[Fe(η²-S₂CH)(dppe)₂][BF₄] respectively. The molecular structure of the former is authenticated by X-ray diffraction analysis.

Full text of DOI:10.1016/S0022-328X(96)06290-0

Products guided by the article

Product name:cis-[Fe(CH=CHCOOMe)(dppe)2]BF₄

Cas No:186519-15-3

R&D Labs maybe for 186519-15-3

Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Hangzhou Neway Chemicals Co., Ltd.

Contact:+86-571-85095566

Address:Room 803, Qinglian Bldg, No 139 Qingchun Road, Hangzhou, Zhejiang China
Taixing Shenfeng Chemical Co., Ltd.

Contact:+86-523-87117033, 87117666

Address:4# Yinsanlu, Huangqiao town, Taixing, Jiangsu, China.

Relevant to this article

Highly regio- And stereoselective synthesis of cyclic carbonates from biomass-derived polyols: Via organocatalytic cascade reaction

Doi:10.1039/c9gc03013a
(2019)
A highly regioselective preparation of 4-chloromethyl-5-methyl-2-aryl-1,3- oxazoles

Doi:10.1002/adsc.200404135
(2004)
Novel selective small molecule agonists for peroxisome proliferator-activated receptor δ (PPARδ) - Synthesis and biological activity

Doi:10.1016/S0960-894X(03)00207-5
(2003)
Thiol ester-boronic acid coupling. A mechanistically unprecedented and general ketone synthesis [18]

Doi:10.1021/ja005613q
(2000)
Soluble polymer-supported chemoenzymatic synthesis of the C₂₁-C₂₇ fragment of the bryostatins

Doi:10.1021/jo005539u
(2000)
Pheromones of pine sawflies: Synthesis of a pure (2S,3R)-3-methylalkan-2-ol stereoisomer via an asymmetric 1,3-dipolar cycloaddition; preparation of a pheromone component of Macrodiprion nemoralis

Doi:10.1055/s-2000-8221
(2000)

Article Doi