186605-72-1Relevant academic research and scientific papers
Methoxycarbonyl-Terminated Dendrons via the Mitsunobu Reaction: An Easy Way to Functionalized Hyperbranched Building Blocks
Hoeger, Sigurd
, p. 20 - 22 (2007/10/03)
Methoxycarbonyl-terminated dendrons can be easily prepared up to the third generation by a convergent approach using the Mitsunobu reaction as the bond-forming step.The advantages of this procedure are that the transformation of the alcohol moiety to a leaving group and its nucleophilic displacement are performed in one pot under mild conditions.
Linked bis-isophthalic acid derivatives as building blocks in the design of self-assembling structures
Zafar, Abdullah,Yang, Ji,Geib, Steven J.,Hamilton, Andrew D.
, p. 2327 - 2330 (2007/10/03)
In this paper we show that linked bis-isophthalic acid derivatives form ordered molecular structures in the solid state. The key organizing interactions are hydrogen bonds between the isophthalate carboxylic acid substituents on adjacent molecules or to methanol solvent. NMR investigations suggest that alternative aggregates form in solution.
