186688-46-0

Basic information

• Product Name: η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]methylpalladium chloride
• CAS NO: 186688-46-0
• Molecular Weight: 524.422
• Mol File: 186688-46-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]methylpalladium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]methylpalladium chloride(186688-46-0)
• EPA Substance Registry System: η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]methylpalladium chloride(186688-46-0)

Safety Data

• Hazardous Substances Data: 186688-46-0(Hazardous Substances Data)

Upstream product

• 186688-44-8 η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]palladium dichloride 
• 676-58-4 methylmagnesium chloride 
• 144404-03-5 (E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine 

Downstream Products

• 186688-48-2 η(1),η(1)-[(E)-((2-pyridyl)methylene)(2,4,6-tri-tert-butylphenyl)phosphine]acetylpalladium chloride 

Relevant articles and documents

Synthesis of 2-(2-pyridyl)phosphaalkenes [Mes*P=C(R)Py] (R = H, SiMe3) and their complexes η1,η1-[Mes*P=C(R)Py]XPdCl (X = Cl, Me, Ac)

Bidentate ligands of the type Mes*P=C(R)Py ((E)-2, R = H; (Z)-9, R = SiMe3; Mes* = supermesityl = 2,4,6-tri-tert-butylphenyl; Py = 2-pyridyl) were synthesized. Ligand (E)-2 was synthesized by reacting Mes*P(Li)SiMe2(t-Bu) (4) with 2-