186759-45-5

Basic information

• Product Name: (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester
• Synonyms: (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester
• CAS NO: 186759-45-5
• Molecular Weight: 221.256
• Mol File: 186759-45-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester(186759-45-5)
• EPA Substance Registry System: (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester(186759-45-5)

Safety Data

• Hazardous Substances Data: 186759-45-5(Hazardous Substances Data)

Upstream product

• 117609-25-3 (S)-(+)-2-amino-1-butanol 
• 501-53-1 benzyl chloroformate 
• 80656-34-4 N-<(benzoyloxy)carbonyl>-D,L-vinylglycine methyl ester 
• 31139-36-3 dibenzyl dicarbonate 
• 99726-03-1 2-aminobut-3-en-1-ol hydrochloride 
• 31037-42-0 hydroxymethyl carbamic acid benzyl ester 
• 67799-92-2 benzyloxycarbonylaminomethyl acetate 

Downstream Products

• 91103-38-7 (R)-(1-hydroxymethallyl)carbamic acid benzyl ester 
• 91028-47-6 (S)-2-<(benzyloxy)carbonyl>amino-3-buten-1-yl acetate 
• 1309370-67-9 3-benzyloxycarbonylamino-4-(2-iodo-phenoxy)-but-1-ene 
• 1309370-74-8 3-benzyloxycarbonylamino-4-(2-iodo-3-nitro-phenoxy)-but-1-ene 
• 1309370-69-1 3-benzyloxycarbonylamino-4-methylen-chromane 
• 1309370-71-5 3-benzyloxycarbonylamino-2-hydro-5H-benzo[b]oxepin-4-one 
• 1309370-70-4 C₁₉H₂₀N₂O₄S 
• 1309370-75-9 3-benzyloxycarbonylamino-4-methylen-5-nitro-chromane 
• 1309370-76-0 C₁₈H₁₈N₂O₃ 
• 1309370-77-1 3-benzyloxycarbonylamino-4-methylen-5-trifluoroacetamide-chromane 
• 1309370-68-0 C₁₉H₂₁IN₂O₄S 
• 271261-18-8 (R)-2-[(benzyloxycarbonyl)amino]-4-(2,4,6-trimethylphenyl)-1-butanol 
• 271261-17-7 (R)-2-[(benzyloxycarbonyl)amino]-4-(2-isopropyl-5-methylphenyl)-1-butanol 
• 271261-14-4 (R)-3-(benzyloxycarbonyl)-4-[2-(4-bromophenyl)ethyl]-2,2-dimethyloxazolidine 

Relevant articles and documents

A novel approach to azasugars from vinyl glycine methyl ester via olefin metathesis

A novel strategy for the synthesis of azasugars from vinyl glycine methyl ester was designed, using an olefin metathesis as a key step. As a first test of this strategy, rac-trans-2-hydroxymethyl-3-hydroxypyrrolidine, which was isolated as the (2R,3S)-iso

An innovative strategy for the synthesis of a new series of potent aminopeptidase (APN or CD13) inhibitors derived from the oxepin-4-one family

Derivatives from the aminobenzosuberone family have been recently synthesized and recognized as highly selective inhibitors of aminopeptidase N (APN)/CD13 (EC 3.4.11.2), an important target for cell migration processes involved in particular in tumor inva

Synthesis of unnatural amino acids via suzuki cross-coupling of enantiopure vinyloxazolidine derivatives

(R and S)-α-Amino alcohols and α-amino acids, including 4-methoxyhomophenylalanine, with a variety of unnatural side chains have been synthesized via palladium-catalyzed cross-coupling Suzuki reactions. The key building blocks 1 and 2, synthesized from the common achiral precursor 2-butene-1,4-diol, were made enantiopure utilizing a Pseudomonas cepacia lipase-catalyzed kinetic resolution. The optimal conditions for the Suzuki cross-coupling and the subsequent oxidations of the resultant α-amino alcohols are described.