186809-13-2

Upstream product

• 922-65-6 divinylcarbinol 
• 110009-21-7 (S)-2-((R)-1-benzyloxy-allyl)-oxirane 
• 100-39-0 benzyl bromide 
• 186809-11-0 (3S,4R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-hex-5-enenitrile 
• 186809-10-9 (3S,4R)-4-Benzyloxy-3-hydroxy-hex-5-enenitrile 
• 102490-00-6 (2S,3R)-1,2-epoxy-4-penten-3-ol 
• 186809-12-1 (3S,4R)-4-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-hexanenitrile 

Downstream Products

• 186809-25-6 C₃₆H₄₇NO₇SSi 
• 186809-24-5 C₃₆H₄₅NO₆SSi 
• 186809-21-2 [(1S,2S,4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-ethynyl-cyclohexyl]-(6-bromo-benzo[1,3]dioxol-5-ylmethyl)-amine 
• 186809-22-3 [(1S,2S,4R,5S)-4-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2-vinyl-cyclohexyl]-(6-bromo-benzo[1,3]dioxol-5-ylmethyl)-amine 
• 186809-23-4 C₂₉H₃₉NO₄Si 
• 186809-16-5 Acetic acid (1S,3R,4S)-3-benzyloxy-4-(tert-butyl-dimethyl-silanyloxy)-5-cyano-1-ethynyl-pentyl ester 

Relevant academic research and scientific papers

Application of a stereospecific intramolecular allenylsilane imino ene reaction to enantioselective total synthesis of the 5,11- methanomorphanthridine class of Amaryllidaceae alkaloids

Enantioselective total syntheses of the pentacyclic 5,11- methanomorphanthridine Amaryllidaceae alkaloids (-)-montanine (1), (-)- coccinine (2), and (-)-pancracine (3) were accomplished using an intramolecular concerted pericyclic allenylsilane imino erie