18699-42-8Relevant articles and documents
Programming of microwave-assisted synthesis of new isophthalate derivatives using ZrOCl2 as a catalyst under solvent-free condition by experimental design
Zolfigol, Mohammad Ali,Khazaei, Ardeshir,Sarmasti, Negin,Seyf, Jaber Yousefi,Khakyzadeh, Vahid,Moosavi-Zare, Ahmad Reza
, p. 142 - 149 (2014/07/21)
In this investigation, isophthalate derivatives were prepared by the reaction of isophthaloyl dichloride with various alcohol derivatives using ZrOCl2 as an efficient, green and a heterogeneous catalyst under microwave irradiation and solvent- free condition. Optimization of the reaction condition was studied by the response surface method (Box Behnken Design (BBD)) with three replicates at a central point for developing a second order model. Predicting response values using the obtained model were in a good accordance with the experimental results. Clean reaction, easy workup procedure, the reusability of the catalyst, short reaction times and high yields were some advantages of this work.
