187029-65-8Relevant articles and documents
On the regiochemistry of nucleophilic attack on 2-halo π-allyl complexes. 4. The effect of silver acetate and nucleophile concentrations in competitive nucleophilic attack with malonate and phenoxide nucleophiles
Organ, Michael G.,Arvanitis, Elena A.,Hynes, Stephen J.
, p. 3918 - 3922 (2003)
2,3-Dibromo-l-propene or its allyl carbonate analogue are ionized under Pd catalysis to generate the 2-bromo Pd-π-allyl complex (triphenylphosphine ligand), which alkylates with malonate nucleophile at the terminal position. The presence of acetate ion in
