692-72-8

Basic information

• Product Name: 2-CHLOROALLYL ACETATE, 97%
• Synonyms: 2-CHLOROALLYL ACETATE, 97%;2-Chloro-2-propenyl acetate;2-Chloro-2-propen-1-ol acetate;Acetic acid 2-chloro-2-propenyl ester
• CAS NO: 692-72-8
• Molecular Formula: C₅H₇ClO₂
• Molecular Weight: 134.56088
• Mol File: 692-72-8.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 145°C at 760 mmHg
• Flash Point: 48.3°C
• Appearance: /
• Density: 1.121 g/mL at 25 °C(lit.)
• Vapor Pressure: 4.96mmHg at 25°C
• Refractive Index: 1.433
• CAS DataBase Reference: 2-CHLOROALLYL ACETATE, 97%(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLOROALLYL ACETATE, 97%(692-72-8)
• EPA Substance Registry System: 2-CHLOROALLYL ACETATE, 97%(692-72-8)

Safety Data

• Hazard Codes: C
• Statements: 10-34-36/37
• Safety Statements: 16-26-27-36/37/39-45
• RIDADR: 2924
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 692-72-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C5H7ClO2/c1-4(6)3-8-5(2)7/h1,3H2,2H3

Upstream product

• 5976-47-6 2-chloroallyl alcohol 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 109391-92-6 (3-acetoxy-2-chloropropyl)phenylselenium dichloride 
• 78-88-6 2,3-Dichloroprop-1-ene 
• 127-08-2 potassium acetate 

Downstream Products

• 187029-65-8 dimethyl (2-chloroprop-2-en-1-yl)(methyl)malonate 
• 403855-58-3 methyl 2-(methylcarboxy)-2-methyl-4-phenoxypent-4-enoate 
• 6148-33-0 ethyl 2,4-dimethylfuran-3-carboxylate 
• 32933-07-6 1-(2,4-dimethyl-furan-3-yl)-ethanone 
• 122570-94-9 [1-(Benzhydrylidene-amino)-3-chloro-but-3-enyl]-phosphonic acid diethyl ester 
• 92825-39-3 2-allyl-2-(2-chloropropenyl)-1,3-cyclohexanedione 
• 92825-40-6 2-prenyl-2-(2-chloropropenyl)-1,3-cyclohexanedione 
• 73336-27-3 2-methyl-2-(2-chloropropenyl)-1,3-cyclohexanedione 

Relevant articles and documents

Sequential Palladium-Catalyzed Allylic Alkylation/retro-Dieckmann Fragmentation Strategy for the Synthesis of α-Substituted Acrylonitriles

A straightforward synthesis of α-substituted acrylonitriles is described using 4-cyano-3-oxotetrahydro-thiophene (c-THT) as an acrylonitrile surrogate. This unprecedented two-step sequence featuring a palladium-catalyzed allylic alkylation (Pd-AA) and a retro-Dieckmann fragmentation provides a general entry into diversely substituted 1,4-dienes.

Highly Enantioselective, Base-Free Synthesis of α-Quaternary Succinimides through Catalytic Asymmetric Allylic Alkylation

The synthesis of diversely substituted five-membered ring succinimide derivatives is reported featuring a direct, base-free, palladium-catalyzed asymmetric allylic alkylation. The method allows a straightforward access to the desired heterocyclic scaffold bearing an all-carbon α-quaternary stereogenic center in high yields and good to excellent enantioselectivities. To further demonstrate the synthetic utility of the method, the allylated products were further converted to various versatile chiral building blocks, including a chiral pyrrolidine and a spirocyclic derivative, using selective transformations.

HYDROLYTIC SELENOXIDE ELIMINATION REACTION FOR THE PREPARATION OF 2-CHLORO-1-OLEFINS

2-Chloro-1-olefins were synthesized in a regiocontrolled way from terminal olefins by a sequence involving Markownikoff-addition of PhSeCl, chlorination of the resulting β-chloroalkyl phenyl selenides with SO2Cl2 and, after recrystallization, hydrolysis/s