187874-87-9

Basic information

• Product Name: ethyl [2-(2,6-dimethyl-4-pyrimidinyl)-2-methylhydrazino]carbothioylcarbamate
• Synonyms: ethyl [2-(2,6-dimethyl-4-pyrimidinyl)-2-methylhydrazino]carbothioylcarbamate
• CAS NO: 187874-87-9
• Molecular Formula: C11H17N5O2S
• Molecular Weight: 283.34998
• Mol File: 187874-87-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ethyl [2-(2,6-dimethyl-4-pyrimidinyl)-2-methylhydrazino]carbothioylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl [2-(2,6-dimethyl-4-pyrimidinyl)-2-methylhydrazino]carbothioylcarbamate(187874-87-9)
• EPA Substance Registry System: ethyl [2-(2,6-dimethyl-4-pyrimidinyl)-2-methylhydrazino]carbothioylcarbamate(187874-87-9)

Safety Data

• Hazardous Substances Data: 187874-87-9(Hazardous Substances Data)

Upstream product

• 4472-45-1 4-chloro-2,6-dimethylpyrimidine 
• 16182-04-0 Ethoxycarbonyl isothiocyanate 
• 187874-74-4 1-methyl-1-(2,4-dimethylpyrimidin-6-yl)hydrazine 

Relevant articles and documents

Synthesis, reactions and theoretical studied of triazolotriazolopyrazinium-3-aminides

Triazolopyrimidinium-3-aminides 5a-h have been synthesised by treatment pyridin-6-yl thiosemicarbazide derivatives 7f-n with dicyclohexylcarbodiimide (DCC).The above aminides 5a-h were slowly hydrolysed in water but very rapidly hydrolysed in 5 M aqueous hydrochloric acid to give substituted 1,2,4-triazole derivatives (e.g. 5a,d,g -> 8e,a,f, respectively); related nucleophilic ring-opening reactions occurred when the aminides (cf. 5a-h) were treated with (separately) methanol and ethanol (e.g. 5d->8c and 8d, respectively).A series of analogous triazolopyrazinium-3-aminides 6a-e was prepared following the procedures described above.The pyrazinium aminides 6 are stable in aq. 2 M HCl, and a stable hydrochloride salt 13 was formed from one such substrate 6a.