1879-14-7Relevant academic research and scientific papers
Design of highly selective alkyne hydrothiolation RhI-NHC catalysts: Carbonyl-triggered nonoxidative mechanism
Palacios, Laura,Meheut, Yoann,Galiana-Cameo, María,Artigas, María José,DI Giuseppe, Andrea,Lahoz, Fernando J.,Polo, Victor,Castarlenas, Ricardo,Pérez-Torrente, Jesús J.,Oro, Luis A.
, p. 2198 - 2207 (2017/06/19)
New RhI-IPr (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-carbene) complexes bearing an N,O-pyridine-2-methanolato (N-O) bidentate ligand have been prepared. The carbonyl complex Rh(N-O)(IPr)(CO) efficiently catalyzes the hydrothiolation of
Hydroxo-rhodium-N-heterocyclic carbene complexes as efficient catalyst precursors for alkyne hydrothiolation
Palacios, Laura,Artigas, Maria Jose,Polo, Victor,Lahoz, Fernando J.,Castarlenas, Ricardo,Perez-Torrente, Jesus J.,Oro, Luis A.
, p. 2910 - 2919 (2014/01/06)
The new Rh-hydroxo dinuclear complexes stabilized by an N-heterocyclic carbene (NHC) ligand of type [Rh(μ-OH)(NHC)(η2-olefin)] 2 (coe, IPr (3), IMes (4); ethylene, IPr (5)) are efficient catalyst precursors for alkyne hydrothiolation
Palladium-catalyzed phosphinylthiolation of terminal alkynes
Hoshi, Nobutaka,Kashiwabara, Taigo,Tanaka, Masato
supporting information; experimental part, p. 2078 - 2081 (2012/07/14)
Phosphinylthiolation of terminal alkynes with Ph2P(O)SBu or a related compound proceeds in the presence of a palladium-PEt3 catalyst system. Activity and stereoselectivity are highly dependent on the nature of solvent, ethylbenzene, and n-hexanol (or t-amyl alcohol) being E- and Z-selective, respectively.
