188066-80-0Relevant academic research and scientific papers
Asymmetric photocycloadditions with an optically active allenylsilane: Trimethylsilyl as a removable stereocontrolling group for the enantioselective synthesis of exo-methylenecyclobutanes
Shepard, Mary S.,Carreira, Erick M.
, p. 2597 - 2605 (1997)
Allenylsilanes undergo enantioselective intramolecular photocycloaddition reactions with enones and enoates to give adducts in 76-99% enantiomeric excess and 67-90% yield. The silyl-substituted exo-methylenecyclobutane products undergo protodesilylation t
