188175-50-0Relevant academic research and scientific papers
Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation
Mitra, Mainak,Lloret-Fillol, Julio,Haukka, Matti,Costas, Miquel,Nordlander, Ebbe
, p. 1408 - 1410 (2014)
A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors. This journal is The Royal Society of Chemistry.
