18829-59-9

Usage

Uses

Used in Fragrance Industry:
2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol is used as a fragrance ingredient for its unique scent characteristics, adding depth and complexity to perfumes and other scented products.
Used in Organic Synthesis:
2,3,4,7,8,8a-hexahydro-3,6,8,8-tetramethyl-1H-3a,7-methanoazulen-4-ol is used as a building block in organic synthesis for the creation of other complex organic compounds, leveraging its unique structure and functional groups to form novel molecules with potential applications in various industries.
Further research and analysis are required to fully explore and utilize the potential of this chemical compound in these and other applications.

InChI:InChI=1/C15H24O/c1-9-7-13(16)15-8-11(9)14(3,4)12(15)6-5-10(15)2/h7,10-13,16H,5-6,8H2,1-4H3

Upstream product

• 469-61-4 alpha-cedrene 
• 17194-58-0 2-[(1R)-1,5-dimethylhex-4-enyl]-5-methylphenol 
• 146026-86-0 C₁₇H₂₆O₂ 
• 1262998-09-3 cedrenone 
• 1262789-28-5 C₁₇H₂₄O₃ 
• 1262789-27-4 C₁₂H₁₆O₂ 
• 22567-49-3 (+)-cedrenene 
• 469-61-4 (-)-α-cedrene 
• 30960-39-5 (8aS)-4-oxo-3c,6,8,8-tetramethyl-(8arH)-1,2,3,7,8,8a-hexahydro-3H-3at,7t-methano-azulene; (-)-cedrenone 

Relevant academic research and scientific papers

Cedar camphor derivative as well as preparation method and application thereof

The invention relates to the technical field of synthetic drugs, in particular to a cedar camphor derivative as well as a preparation method and an application thereof. The cedar camphor derivative isany one of compounds shown in the following structural formula, tautomers, hydrates, solvates or pharmaceutically acceptable salts thereof, and the cedar camphor derivative has a good treatment effect on viruses, especially influenza viruses, so that the application range of the cedar camphor and the derivatives thereof is expanded, and the variety of the cedar camphor derivatives is expanded.

Novel and versatile photosensitized oxygenation reaction of α-cedrene

Three types of photosensitized oxygenations of α-cedrene (CED) were investigated, including: rose bengal(RB)-sensitized photooxygenation of α-cedrene in acetonitrile produced one major stereospecific product (cedr-8-exoen-9α-ol), in which the double bond migrated to an adjacent position, this result demonstrated the singlet oxygen process; 9,10-dicyanoanthrathene (DCA) sensitized photooxygenation led to the formation of cedr-8-en-10β-ol; benzyl (BZ)-sensitized photoepoxidation furnished a stereospecific 8α,9α-cedrene epoxide, this reaction includes radical reaction mechanism.

An oxidative dearomatization-induced [5 + 2] cascade enabling the syntheses of α-cedrene, α-pipitzol, and sec -cedrenol

Efficient syntheses of α-cedrene (1), α-pipitzol (2), and sec-cedrenol (3) were carried out using a new method, which was inspired by the proposed biosynthesis of the tricyclic skeleton of cedrol (12). The key transformation begins with the oxidative dearomatization of curcuphenol (5a) followed by an intramolecular [5 + 2] cycloaddition of the respective phenoxonium intermediate across the tethered olefin. The benzylic stereocenter effectively guides the formation of the first two stereocenters during the [5 + 2] reaction. The cascade then terminates with the selective incorporation of acetic acid to generate a third stereocenter, setting it apart from other previous cationic [5 + 2] reactions. The phenolic precursors (5a-h) are constructed from readily available salicylaldehydes, either as the racemate (one pot) or as a specific enantiomer (four pots) by a modification to our method for the generation of ortho-quinone methides (o-QMs).