17194-58-0Relevant articles and documents
Expedient synthesis of (R)-curcuphenol: A chiral pool strategy
Feng, Jing,Zhu, Guili,Liu, Bo,Zhou, Xiangdong
, p. 23 - 26 (2013)
Curcuphenol is an interesting sesquiterpenoid with diverse bioactivities. Exploration of a concise and scalable synthetic route is still of significance in spite that many asymmetric total syntheses have been achieved. We report an expedient asymmetric synthesis of (R)-curcuphenol from citronellal, which features only two purification operations in the overall six-step synthesis. Curcuphenol is an interesting terpenoid with diverse bioactivities. We report an expedient asymmetric synthesis of curcuphenol from citronellal which features only two purification operations in the overall six-step synthesis. Copyright
Total Synthesis of (-)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane
Coffinier, Romain,Assal, Mourad El,Peixoto, Philippe A.,Bosset, Cyril,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Pouységu, Laurent,Quideau, Stéphane
supporting information, p. 1120 - 1123 (2016/03/15)
The first total and biomimetic synthesis of the natural bis(sesquiterpene) (-)-bacchopetiolone (revised structure) was completed through a highly diastereoselective hydroxylative phenol dearomatization/[4+2]-dimerization cascade conversion of (+)-curcuphe
Application of the lithiation-borylation reaction to the rapid and enantioselective synthesis of the bisabolane family of sesquiterpenes
Aggarwal, Varinder K.,Ball, Liam T.,Carobene, Simon,Connelly, Rickki L.,Hesse, Matthew J.,Partridge, Benjamin M.,Roth, Philippe,Thomas, Stephen P.,Webster, Matthew P.
, p. 9230 - 9232 (2012/09/10)
The expedient enantioselective synthesis of 5 bisabolane sesquiterpenes has been achieved using a common, one-pot lithiation-borylation reaction of secondary benzylic carbamates and either protodeboronation or oxidation to give the natural products in few
