188343-69-3

Upstream product

• 100-39-0 benzyl bromide 
• 188359-82-2 3-((4S,5R,4'R)-2,2,2',2'-Tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-propan-1-ol 
• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 
• 188343-68-2 methyl 3-((4S,4'R,5R)-2,2,2',2'-tetramethyl-[4,4'-bi(1,3-dioxolan)]-5-yl)propanoate 
• 65371-70-2 methyl 2,3-dideoxy-4,5:6,7-di-O-isopropylidene-D-arabino-hept-2-enonate 

Downstream Products

• 188343-72-8 (2R,3S,4R)-7-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-heptane-2,3,4-triol 
• 188343-64-8 (2R,3S,4R)-7-benzyloxy-1,2,3,4-tetrahydroxyheptane 
• 188343-70-6 (R)-1-[(4R,5R)-5-(3-Benzyloxy-propyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-ethane-1,2-diol 

Relevant academic research and scientific papers

Use of aldolases in the synthesis of non-carbohydrate natural products. Stereoselective synthesis of aspicilin C-3-C-9 fragment

The C-3-C-9 man fragment of aspicilin was prepared via a fructose 1,6-diphosphate aldolase reaction. The same fragment was also synthesized by chemical transformation starting from D-arabinose. The C-3 - C-9 main fragment of aspicilin was prepared via a fructose 1,6-diphosphate aldolase reaction. The same fragment was also synthesized by chemical transformation starting from D-arabinose.