188427-79-4Relevant academic research and scientific papers
Modulation and binding properties of extended glycoluril molecular clips
Polavarapu, Prasad,Melander, Helena,Langer, Vratislav,Gogoll, Adolf,Grennberg, Helena
, p. 643 - 651 (2008)
A glycoluril clip (1) provides a deep cavity for binding of guest molecules. Guest species interact preferentially via hydrogen bonding or ion-lone pair interactions. Complexation-induced conformational modulation of the cavity wall distance was observed.
Synthesis and X-ray structure of a novel cavity-containing dinuclear nickel(II) complex
Gosling, P. A.,Sijbesma, R. P.,Spek, A. L.,Nolte, R. J. M.
, p. 404 - 406 (2007/10/02)
Compounds consisting of a substrate-binding site and a NiII or MnIII salen moiety have been synthesized.These compounds are able to epoxidise a variety of alkenes in the presence of sodium hypochlorite or iodosylbenzene.The X-ray structure of the nickel(II) complex is reported.
