188444-20-4Relevant articles and documents
Asymmetric synthesis of 5,5-disubstituted thiotetronic acids using an allyl xanthate to dithiocarbonate rearrangement: Total synthesis of (55)-thiolactomycin with revision of the absolute configuration of the natural product
Chambers, Mark S.,Thomas, Eric J.
, p. 417 - 431 (2007/10/03)
An asymmetric synthesis of thiotetronic acids related to the antibiotics thiolactomycin 1 and thiotetromycin 2 has been developed in which the key step is a stereoselective [3.3]-rearrangement of an allyl xanthate to the corresponding dithiocarbonate. Thu