Cas 188485-37-2,(CH3)Ti((NC6H3(CH(CH3)2)2)2(CH2)3)(1+)*CH3B(C6F5)3(1-)=[(CH3)Ti((NC6H3(CH(CH3)2)2)2(CH2)3)][CH3B(C6F5)3]

188485-37-2

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Product Name: (CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=[(CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)][CH₃B(C₆F₅)3]
Synonyms:
CAS NO:188485-37-2
Molecular Formula:
Molecular Weight: 982.563
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: (CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=[(CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)][CH₃B(C₆F₅)3](CAS DataBase Reference)
NIST Chemistry Reference: (CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=[(CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)][CH₃B(C₆F₅)3](188485-37-2)
EPA Substance Registry System: (CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)⁽¹⁺⁾*CH₃B(C₆F₅)3^(1-)=[(CH₃)Ti((NC₆H₃(CH(CH₃)2)2)2(CH₂)3)][CH₃B(C₆F₅)3](188485-37-2)

Safety Data

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Safety Statements: N/A
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RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 188485-37-2(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 188485-37-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,8,4,8 and 5 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 188485-37:
(8*1)+(7*8)+(6*8)+(5*4)+(4*8)+(3*5)+(2*3)+(1*7)=192
192 % 10 = 2
So 188485-37-2 is a valid CAS Registry Number.

188485-37-2Upstream product

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188485-37-2Relevant academic research and scientific papers

Living polymerization of α-olefins: Catalyst precursor deactivation via the unexpected cleavage of a B-C6F5 bond

Scollard, John D.,McConville, David H.,Rettig, Steven J.

, p. 1810 - 1812 (1997)

The titanium diamide complex [ArN(CH2)3-NAr]TiMe2 (1a; Ar = 2,6-iPr2C6H3) reacts with B(C6F5)3 in pentane to give an insoluble yellow-orange solid (2a). Complex 2a is a catalyst for the living polymerization of 1-hexene. Pentane suspensions of 2a slowly evolve methane over the course of several hours to give the new pentane-soluble derivative [ArN(CH2)3NAr]Ti[CH2B-(C6F 5)2](C6F5) (3a), which was structurally characterized. Addition of a B-C6F5 group across an intermediate Ti=CH2 unit is proposed. Compound 3a is inactive for the polymerization of α-olefins.

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