188658-45-9

Basic information

• Product Name: di-μ-chlorotetrachlorobis(2-tetrahydrofurfuryloxo-O,O')dititanium(IV)
• Synonyms: di-μ-chlorotetrachlorobis(2-tetrahydrofurfuryloxo-O,O')dititanium(IV)
• CAS NO: 188658-45-9
• Molecular Weight: 510.729
• Mol File: 188658-45-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: di-μ-chlorotetrachlorobis(2-tetrahydrofurfuryloxo-O,O')dititanium(IV)(CAS DataBase Reference)
• NIST Chemistry Reference: di-μ-chlorotetrachlorobis(2-tetrahydrofurfuryloxo-O,O')dititanium(IV)(188658-45-9)
• EPA Substance Registry System: di-μ-chlorotetrachlorobis(2-tetrahydrofurfuryloxo-O,O')dititanium(IV)(188658-45-9)

Safety Data

• Hazardous Substances Data: 188658-45-9(Hazardous Substances Data)

Upstream product

• 176434-85-8 [TiCl₃(C₄H₈O)(OCH₂CH(CH₂)3O)] 
• 7550-45-0 titanium tetrachloride 

Relevant articles and documents

New 2-tetrahydrofurfuryloxotitanium(IV) intermediates for the synthesis of olefin polymerization catalysts

The complexes [TiCl3(tmen){η1-OCH2CH(CH2) 3O}] 1, [Ti2(μ-Cl)2Cl4{η2-OCH 2CH(CH2)3O}2] 2 and [TiCl4(tmen)] 3 (tmen = Me2NCH2CH2NMe2) have been synthesized and structurally characterized by X-ray diffraction. The crystals of 1 consist of monomeric [TiCl3(tmen){η1-OCH2CH(CH2) 3O}] molecules. Three chloride, one oxygen and two nitrogen atoms form a distorted octahedron around the titanium atom. Compound 2 has a dimeric structure. Each titanium atom is surrounded by two bridging chloride atoms, two terminal chloride atoms and two oxygen atoms of the 2-tetrahydrofurfuryloxide ligand. The crystals of compound 3 consist of monomeric molecules in which four terminal chloride atoms and two nitrogen atoms from the chelate tmen ligand form a distorted octahedron around Ti. High catalytic activity was found for 1 and 2.