18868-46-7

Usage

Uses

Used in Chemical Synthesis Industry:
2,2,2-Trichloroethyl dichlorophosphate is used as a chemical intermediate for the production of organophosphorus compounds, which are essential in the manufacturing of pesticides and flame retardants. Its role in these processes is crucial for the development of effective and safe products in these industries.

InChI:InChI=1/C10H9N3O2/c14-13(15)10-3-1-9(2-4-10)7-12-6-5-11-8-12/h1-6,8H,7H2

Upstream product

• 115-20-8 1,1,1-trichloroethanol 

Downstream Products

• 306-52-5 2,2,2-trichloroethyl dihydrogen phosphate 
• 112104-67-3 (Benzyl-2,3,4-tri-O-benzyl-α-D-glucopyranosid-6)-(2,2,2-trichlorethyl)-(triethylammonium)-phosphat 
• 133992-67-3 C₆₅H₆₇Cl₃N₅O₂₁P 
• 110434-99-6 (1,5-Di-O-benzoyl-2,3-O-isopropyliden-β-D-fructopyranosid-4)(2,2,2-trichlorethyl)(triethylammonium)phosphat 
• 110434-97-4 (exo-Benzyl-3,4-O-benzyliden-β-L-arabinopyranosid-2)(2,2,2-trichlorethyl)(triethylammonium)phosphat 
• 112104-69-5 (endo-1,2:4,6-Di-O-benzyliden-α-D-glucopyranose-3)-(2,2,2-trichlorethyl)-(triethylammonium)-phosphat 
• 900180-52-1 8-azido-3,6-dioxaoctyl 2-acetamido-6-O-benzyl-3-O-(3-O-benzyl-β-D-galactopyranosyl-(S)-P-4,6-cyclic 2,2,2-trichloroethyl phosphate)-2-deoxy-β-D-glucopyranoside 
• 900180-47-4 8-azido-3,6-dioxaoctyl 2-acetamido-6-O-benzyl-3-O-(3-O-benzyl-β-D-galactopyranosyl-(R)-P-4,6-cyclic 2,2,2-trichloroethyl phosphate)-2-deoxy-β-D-glucopyranoside 
• 79970-38-0 S,S-diphenyl 2,2,2-trichloroethyl phosphorodithioate 
• 64350-14-7 2,2,2-Trichlorethylphosphoranilidochloridat 

Relevant academic research and scientific papers

Evaluation of Natural and Synthetic Phosphate Donors for the Improved Enzymatic Synthesis of Phosphate Monoesters

Undesired product hydrolysis along with large amounts of waste in form of inorganic monophosphate by-product are the main obstacles associated with the use of pyrophosphate in the phosphatase-catalyzed synthesis of phosphate monoesters on large scale. In order to overcome both limitations, we screened a broad range of natural and synthetic organic phosphate donors with several enzymes on a broad variety of hydroxyl-compounds. Among them, acetyl phosphate delivered stable product levels and high phospho-transfer efficiency at the lower functional pH-limit, which translated into excellent productivity. The protocol is generally applicable to acid phosphatases and compatible with a range of diverse substrates. Preparative-scale transformations using acetyl phosphate synthesized from cheap starting materials yielded multiple grams of various sugar phosphates with up to 433 g L?1 h?1 space-time yield and 75% reduction of barium phosphate waste. (Figure presented.).

A NEW CONVENIENT METHOD FOR β-LACTAM FORMATION FROM β-AMINO ACIDS USING BIS(5'-NITRO-2'-PYRIDYL) 2,2,2-TRICHLOROETHYL PHOSPHATE

Bis(5'-nitro-2'-pyridyl) 2,2,2-trichloroethyl phosphate is found to be a new efficient condensing agent for β-lactam formation from β-amino acids in acetonitrile.

O-Trihaloethyl phosphorodithioate pesticides

Compounds of the formula STR1 in which X is halogen and R1 and R2 are each alkyl groups, insecticidal, acaricidal and nematicidal compositions thereof, and a method for controlling such pests are disclosed.