188713-27-1

Basic information

• Product Name: N,N-bis(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine
• Synonyms: N,N-bis(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine
• CAS NO: 188713-27-1
• Molecular Weight: 524.831
• Mol File: 188713-27-1.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: N,N-bis(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine(188713-27-1)
• EPA Substance Registry System: N,N-bis(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine(188713-27-1)

Safety Data

• Hazardous Substances Data: 188713-27-1(Hazardous Substances Data)

Upstream product

• 50-00-0 formaldehyd 
• 96-76-4 2,4-di-tert-Butylphenol 
• 110-70-3 N,N`-dimethylethylenediamine 
• 108-00-9 N,N-dimethylethylenediamine 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 38946-25-7 N-(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylenediamine 

Downstream Products

• 1445613-76-2 ((CH₃)2NC₂H₄N(CH₂C₆H₂(C(CH₃)3)2O)2)ZrBn₂ 
• 267428-16-0 Zr(tBu-ONNMe₂O)Bn₂ 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 38946-25-7 N-(3,5-di-t-butyl-2-hydroxybenzyl)-N',N'-dimethylenediamine 
• 1402853-98-8 (Me₂NCH₂CH₂N{CH₂(2-OC₆H₂Bu^t₂-3,5)}₂)Y(OCH₂Ph)(THF) 
• 405065-41-0 ((C₄H₉)2C₆H₂OCH₂)2NC₂H₄N(CH₃)2Hf(CH₂C₆H₅)⁽¹⁺⁾*C₆H₅CH₂B(C₆F₅)3^(1-)=((C₄H₉)2C₆H₂OCH₂)2NC₂H₄N(CH₃)2Hf(CH₂C₆H₅)2B(C₆F₅)3 
• 405065-37-4 ((C₄H₉)2C₆H₂OCH₂)2NC₂H₄N(CH₃)2Zr(CH₂C₆H₅)⁽¹⁺⁾*C₆H₅CH₂B(C₆F₅)3^(1-)=((C₄H₉)2C₆H₂OCH₂)2NC₂H₄N(CH₃)2Zr(CH₂C₆H₅)2B(C₆F₅)3 
• 1244762-82-0 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Yb(2,6-diisopropylphenolate)(THF)] 
• 1244762-92-2 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Y(4-methylphenolate)(THF)] 
• 1244762-75-1 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Nd(2,6-diisopropylphenolate)(THF)] 
• 1244762-85-3 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Nd(4-methylphenolate)(THF)2] 
• 1244762-78-4 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Sm(2,6-diisopropylphenolate)(THF)] 
• 1244762-88-6 [(Me₂NCH₂CH₂N(CH₂-(2-O-C₆H₂tBu₂-3,5))2)Sm(4-methylphenolate)(THF)2] 

Relevant articles and documents

Ring-opening polymerization of lactide with group 3 metal complexes supported by dianionic alkoxy-amino-bisphenolate ligands: Combining high activity, productivity, and selectivity

A series of new alkoxy-amino-bis(phenols) (H2L 1-6) has been synthesized by Mannich condensations of substituted phenols, formaldehyde, and amino ethers or diamines. The coordination properties of these dianionic ligands towards yttrium, lantha

Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization of rac-lactide and rac-β-butyrolactone

Eight rare-earth metal guanidinates supported by a versatile family of chelating amine-bridged bis(phenolate) ligands were synthesized. Metathesis reactions of rare-earth metal chlorides [LnClL1(THF)] stabilized by amine-bridged bis(phenolate)

Vanadium aminophenolates in catechol oxidation: Conformity with Finke's common catalyst hypothesis

Six known aminophenolate vanadium complexes V1-V6 were examined in 3,5-di-tert-butylcatechol (1, 3,5-DTBC) oxidation. From the complexes V1-V5 have been previously shown to demonstrate catechol oxidase (catecholase) like behavior, catalytically oxidizing 1 to 3,5-di-tert-butyl-1,2-benzoquinone (2, 3,5-DTBQ). A critical re-evaluation of V1-V5, including V6 not assessed earlier, in the aerobic oxidation of 1 has revealed that several catechol dioxygenase products are obtained in addition to 2, which is produced partly by autoxidation. Mechanistic investigations into the V1-V6 catalyzed oxidation of 1 by EPR, negative mode ESI-MS and 51V NMR, in addition to semi-quantitative product distribution analyses with GC and column chromatography afford compelling evidence in support of the "common catalyst hypothesis"earlier proposed by Finke and co-workers. During the reaction, V1-V6 are partially converted in situ by H2O2 assisted leaching to vanadium catecholate complexes [V(3,5-DTBC)2(3,5-DTBSQ)] and [VO(3,5-DTBC)(3,5-DTBSQ)], where 3,5-DTBSQ = 3,5-di-tert-butyl-1,2-semiquinone, the latter of which has been implicated as the common true active catalyst in catechol dioxygenation as per the common catalyst hypothesis. The results herein suggest that vanadium aminophenolate complexes are sensitive to H2O2 mediated leaching in the presence of strong σ and π donating ligands such as 1 and 2. Furthermore, based on these results, the use of vanadium aminophenolate complexes as catechol oxidase mimics is not as warranted as previously understood.

Isoselective Ring-Opening Polymerization of rac-Lactide Catalyzed by Sodium/potassium Tetradentate Aminobisphenolate Ion-paired Complexes

Two sodium/potassium tetradentate aminobisphenolate ion-paired complexes were synthesized and structurally characterized. These ion-paired complexes are efficient catalysts for the ring-opening polymerization of rac-lactide (rac-LA) in the presence of 5 equivalents BnOH as an initiator and the side reaction of epimerization can be suppressed well at low temperatures. The polymerizations are controllable, affording polylactides with desirable molecular weights and narrow molecular weight distributions; the highest molecular weight can reach 50.1 kg mol?1 in this system, and a best isoselectivity of Pm=0.82 was achieved. Such polymerizations have rarely been reported for isoselective sodium/potassium complexes without crown ether as an auxiliary ligand. The solid structures suggest that BnOH can be activated by an interaction with the anion of sodium/potassium complex via a hydrogen bond and that the monomer is activated by coordination to sodium/potassium ion.

Ligand-Induced Tuning of the Oxidase Activity of μ-Hydroxidodimanganese(III) Complexes Using 3,5-Di-tert-butylcatechol as the Substrate: Isolation and Characterization of Products Involving an Oxidized Dioxolene Moiety

Oxidase activities of a μ-hydroxidodimanganese(III) system involving a series of tetradentate capping ligands H2LR1,R2 with a pair of phenolate arms have been investigated in the presence of 3,5-di-tert-butylcatechol (Hsu