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  • 108-00-9 Structure
  • Basic information

    1. Product Name: N,N-Dimethylethylenediamine
    2. Synonyms: N-(2-Aminoethyl)-N,N-dimethylamine;N,N-Dimethyl-1,2-diaminoethane;N,N'-Dimethyl-1,2-ethandiamine;N,N-Dimethyl-1,2-ethylenediamine;ACRYLIC ACID 2-(DIMETHYLAMINO)ETHYL ESTER;ACRYLIC ACID 2-(N,N-DIMETHYLAMINO)ETHYL ESTER;2-(DIMETHYLAMINO)ETHYL ACRYULATE;2-DIMETHYLAMINOETHYLAMINE
    3. CAS NO:108-00-9
    4. Molecular Formula: C4H12N2
    5. Molecular Weight: 88.15
    6. EINECS: 203-541-2
    7. Product Categories: Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Polyamines
    8. Mol File: 108-00-9.mol
    9. Article Data: 29
  • Chemical Properties

    1. Melting Point: -70 °C
    2. Boiling Point: 64 °C12 mm Hg(lit.)
    3. Flash Point: 75 °F
    4. Appearance: Clear colorless to pale yellow/Liquid
    5. Density: 0.807 g/mL at 20 °C(lit.)
    6. Vapor Pressure: 0.35 psi ( 20 °C)
    7. Refractive Index: n20/D 1.438(lit.)
    8. Storage Temp.: Flammables area
    9. Solubility: N/A
    10. PKA: 9.59±0.10(Predicted)
    11. Explosive Limit: 1.3-10.8%(V)
    12. Water Solubility: MISCIBLE
    13. Sensitive: Hygroscopic
    14. BRN: 605279
    15. CAS DataBase Reference: N,N-Dimethylethylenediamine(CAS DataBase Reference)
    16. NIST Chemistry Reference: N,N-Dimethylethylenediamine(108-00-9)
    17. EPA Substance Registry System: N,N-Dimethylethylenediamine(108-00-9)
  • Safety Data

    1. Hazard Codes: T+,F,C
    2. Statements: 24/25-26-34-35-21/22-11-36/37-10
    3. Safety Statements: 26-28-36/37/39-45-36-28A-23-16
    4. RIDADR: UN 3302 6.1/PG 2
    5. WGK Germany: 2
    6. RTECS: KH8608250
    7. F: 8
    8. TSCA: Yes
    9. HazardClass: 3
    10. PackingGroup: II
    11. Hazardous Substances Data: 108-00-9(Hazardous Substances Data)

108-00-9 Usage

Chemical Properties

clear colorless to pale yellow liquid

Uses

Different sources of media describe the Uses of 108-00-9 differently. You can refer to the following data:
1. It finds its application as an intermediate in the synthesis of Cefotiam. It is also used as a catalyst in the synthesis of allylic nitro compounds.
2. N,N-Dimethylethylenediamine is a bidentate ligand that can be used:To synthesize Schiff base ligands to prepare their zinc alkyl and zinc alkoxide complexes that initiate ring-opening polymerization of lactides.As a ligand to prepare copper azido polymers.In the synthesis of naphthalimides such as amonafide, an antitumor agent.As the receptor in building fluorescent signaling systems to perturb the photoinduced intramolecular electron transfer (PET) process from the nitrogen lone-pair to the fluorophore.

Check Digit Verification of cas no

The CAS Registry Mumber 108-00-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 8 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 108-00:
(5*1)+(4*0)+(3*8)+(2*0)+(1*0)=29
29 % 10 = 9
So 108-00-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H12N2/c1-6(2)4-3-5/h3-5H2,1-2H3/p+2

108-00-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (B20182)  N,N-Dimethylethylenediamine, 97%   

  • 108-00-9

  • 50g

  • 382.0CNY

  • Detail
  • Alfa Aesar

  • (B20182)  N,N-Dimethylethylenediamine, 97%   

  • 108-00-9

  • 100g

  • 728.0CNY

  • Detail
  • Alfa Aesar

  • (B20182)  N,N-Dimethylethylenediamine, 97%   

  • 108-00-9

  • 250g

  • 1616.0CNY

  • Detail
  • Aldrich

  • (39030)  N,N-Dimethylethylenediamine  ≥98.0% (GC)

  • 108-00-9

  • 39030-100ML

  • 1,021.41CNY

  • Detail
  • Aldrich

  • (39030)  N,N-Dimethylethylenediamine  ≥98.0% (GC)

  • 108-00-9

  • 39030-500ML

  • 3,229.20CNY

  • Detail
  • Aldrich

  • (D158003)  N,N-Dimethylethylenediamine  95%

  • 108-00-9

  • D158003-25G

  • 270.27CNY

  • Detail
  • Aldrich

  • (D158003)  N,N-Dimethylethylenediamine  95%

  • 108-00-9

  • D158003-100G

  • 1,202.76CNY

  • Detail

108-00-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Dimethylaminoethylamine

1.2 Other means of identification

Product number -
Other names DIMETHYLAMINO ETHYLAMINE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:108-00-9 SDS

108-00-9Related news

Hetero-octanuclear cubane-like and one-dimensional cyano complexes with the N,N-Dimethylethylenediamine (cas 108-00-9) ligand08/20/2019

A series of complexes containing dmen (dmen = N,N-dimethylethylenediamine) units and cyano groups, namely bimetallic octanuclear and binuclear [Zn4(dmen)8Ni4(CN)16] (1), [Cd4(dmen)8Ni4(CN)16] (2), [Zn(dmen)2Pd(μ-CN)2(CN)2] (3) and [Cd(dmen)2Pd(μ-CN)2(CN)2] (4), have been synthesized and charac...detailed

108-00-9Relevant articles and documents

A new class of histamine H3-receptor antagonists: Synthesis and structure - Activity relationships of 7,8,9,10-Tetrahydro-6H-cyclohepta[b]quinolines

Turner, Sean C.,Esbenshade, Timothy A.,Bennani, Youssef L.,Hancock, Arthur A.

, p. 2131 - 2135 (2003)

The synthesis and biological evaluation of novel cycloheptaquinoline antagonists of the human H3 receptor are described. Two series of compounds, bearing either an amino substituent or an alkyne linker at the 11-position, were investigated. Modifications of the amino substituents, optimization of chain length and the effect of conformational restraints are described. Several compounds with high affinity and selectivity for the H3 receptor were discovered.

One-step synthesis of 6-acetamido-3-(N-(2-(dimethylamino) ethyl) sulfamoyl) naphthalene-1-yl 7-acetamido-4-hydroxynaphthalene-2-sulfonate and its characterization with 1D and 2D NMR techniques

Zhang, Wei

, p. 431 - 434 (2013)

A one-step method was reported for the synthesis of 6-acetamido-3-(N-(2- (dimethylamino) ethyl) sulfamoyl) naphthalene-1-yl 7-acetamido-4- hydroxynaphthalene-2-sulfonate by treating 7-acetamido-4-hydroxy-2- naphthalenesulfonyl chloride with equal moles of N, N-dimethylethylenediamine in acetonitrile in the presence of K2CO3. The chemical structure of the obtained compounds was characterized by MS, FTIR, 1H NMR, 13C NMR, gCOSY, TOCSY, gHSQC, and gHMBC. The chemical shift differences of 1H and 13C being δ 0.04 and 0.2, respectively, were unambiguously differentiated. Copyright 2013 John Wiley & Sons, Ltd. 6-Acetamido-3-(N-(2-(dimethylamino) ethyl) sulfamoyl) naphthalene-1-yl 7-acetamido-4-hydroxynaphthalene-2-sulfonate was prepared by a one-step method. The structure of the compound was elucidated by 1D and 2D NMR. The chemical shift differences of 1H and 13C being δ 0.04 and 0.2, respectively, were unambiguously differentiated. Copyright

-

Price,C.C. et al.

, p. 650 - 655 (1965)

-

Isoflavone amide type derivative, preparation method and medical application thereof

-

Paragraph 0016; 0092; 0093; 0094; 0100; 0101; 0102, (2016/10/10)

The invention relates to the field of medicinal chemistry, and relates to an isoflavone amide type derivative, a preparation method and a medical application thereof, in particular to an isoflavone amide type derivative with the general formula (I), a preparation method thereof, medicine compositions including the isoflavone amide type derivative and a medical application thereof, especially an application of the isoflavone amide type derivative as a medicine for preventing or curing hyperlipemia, obesity or type II diabetes. The general formula (I) is shown in the description.

Applications of dynamic combinatorial chemistry for the determination of effective molarity

Ciaccia, Maria,Tosi, Irene,Baldini, Laura,Cacciapaglia, Roberta,Mandolini, Luigi,Di Stefano, Stefano,Hunter, Christopher A.

, p. 144 - 151 (2015/02/19)

A new strategy for determining thermodynamic effective molarities (EM) for macrocylisation reactions using dynamic combinatorial chemistry under dilute conditions is presented. At low concentrations, below the critical value, Dynamic Libraries (DLs) of bifunctional building blocks contain only cyclic species, so it is not possible to quantify the equilibria between linear and cyclic species. However, addition of a monofunctional chain stopper can be used to promote the formation of linear oligomers allowing measurement of EM for all cyclic species present in the DL. The effectiveness of this approach was demonstrated for DLs generated from mixtures of 1,3-diimine calix[4]arenes, linear diaminoalkanes and monoaminoalkanes. For macrocycles deriving from one bifunctional calixarene and one diamine, there is an alternating pattern of EM values with the number of methylene units in the diamine: odd numbers give significantly higher EMs than even numbers. For odd numbers of methylene units, the alkyl chain can adopt an extended all anti conformation, whereas for even numbers of methylene units, gauche conformations are required for cyclisation, and the associated strain reduces EM. The value of EM for the five-carbon linker indicates that this macrocycle is a strainless ring. This journal is

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