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Usage

Uses

Used in Adhesives and Sealants Industry:
TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& is used as a coupling agent to improve the adhesion of organic polymer resins to inorganic materials, thereby enhancing the performance and durability of adhesives and sealants.
Used in Coatings Industry:
In the coatings industry, TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& serves as a surface modifier and adhesion promoter, ensuring better bonding between the coating and the substrate, leading to improved durability and resistance to environmental factors.
Used in Silicone Polymer Production:
TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& is utilized in the production of silicone polymers, contributing to the development of materials with unique properties such as heat resistance, flexibility, and chemical stability.
Used in Pharmaceutical and Agrochemical Synthesis:
TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& plays a role in the synthesis of pharmaceuticals and agrochemicals, where its unique structure can be leveraged to create novel compounds with potential therapeutic or pesticidal properties.
TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& is used as a research compound in the fields of materials science, industrial chemistry, and pharmaceutical research for its potential applications in developing new materials and products with improved performance characteristics.

InChI:InChI=1/C13H19F3O3Si/c1-4-17-20(18-5-2,19-6-3)12-9-7-11(8-10-12)13(14,15)16/h7-10H,4-6H2,1-3H3

Upstream product

• 78-10-4 tetraethoxy orthosilicate 
• 402-43-7 p-trifluoromethylphenyl bromide 

Downstream Products

• 142557-76-4 4-acetyl-4'-trifluoromethylbiphenyl 
• 426823-25-8 3-(4-trifluoromethyl-phenyl)-pyridine 
• 647842-34-0 ethyl 4'-(trifluoromethyl)-[1,1'-biphenyl]-4-carboxylate 
• 1099595-83-1 6-(4-trifluoromethylphenyl)quinoline 
• 1009026-35-0 phenyl[4'-(trifluoromethyl)[1,1'-biphenyl]-4-yl]methanone 
• 460743-71-9 2-(4-(trifluoro-methyl)phenyl)naphthalene 
• 1099595-82-0 4-trifluoromethyl-1-(3,4-methylenedioxyphenyl)lbenzene 
• 455-18-5 4-CF₃C₆H₄CN 
• 581-80-6 4,4'-bis(trifluoromethyl)biphenyl 
• 545396-54-1 2-chloro-4-[4-(trifluoromethyl)phenyl]pyridine 
• 53344-74-4 2,2′-dichloro-4,4′-bipyridinyl 
• 77918-46-8 diethyl (4-(trifluoromethyl)phenyl)-phosphonate 
• 1203793-21-8 10-[4-(trifluoromethyl)phenyl]benzo[h]quinoline 
• 1234908-22-5 ethyl 2-fluoro-2-[4-(trifluoromethyl)phenyl]acetate 

Relevant academic research and scientific papers

Rhodium(III)-Catalyzed Direct C-H Arylation of Various Acyclic Enamides with Arylsilanes

The stereoselective β-C(sp2)-H arylation of various acyclic enamides with arylsilanes via Rh(III)-catalyzed cross-coupling reaction was illustrated. The methodology was characterized by extraordinary efficacy and stereoselectivity, a wide scope of substrates, good functional group tolerance, and the adoption of environmentally friendly arylsilanes. The utility of this present method was evidenced by the gram-scale synthesis and further elaboration of the product. In addition, Rh(III)-catalyzed C-H activation is considered to be the critical step in the reaction mechanism.

Ligand-promoted oxidative cross-coupling of aryl boronic acids and aryl silanes by palladium catalysis

The first cross-coupling reaction between aryl silanes and aryl boronic acids is described. This transformation represents one of the very few examples of coupling reactions between two nucleophilic organometallic reagents and provides a new method for the formation of biaryl compounds. The successful development of this reaction was enabled by the use of commercially available 2,2-bis(diphenylphosphino)-1,1-binaphthyl (BINAP) as the ligand. A small amount of BINAP (3 mol %) was sufficient to suppress the formation of the homocoupling products, and the reaction yielded the cross-coupling products with high selectivity under mild conditions, even when the ratio of the two coupling partners was 1:1.

A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction

A series of aryltriethoxysilanes was synthesized from the reaction mixture of aryl bromide, Mg powder, 1,2-dibromoethane and tetraethyl orthosilicate in THF under ultrasound. This sonochemical Barbier-type reaction provides a simple and efficient method for preparation of aryltriethoxysilanes. The Hiyama cross-coupling reaction of phenyltriethoxysilane with bromobenzene was investigated under different palladium catalysts and Pd(PhCN)2Cl2 was found to be the best choice.

Palladium-catalyzed cross-coupling reaction of aryltriethoxysilanes with aryl bromides under basic aqueous conditions

Aryltriethoxysilanes were cross-coupled with aryl bromides in high yield in the presence of a palladium catalyst and aqueous sodium hydroxide.