188748-63-2

Basic information

• Product Name: TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL&
• Synonyms: TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL&;1-TRIETHOXYSILYL-4-TRIFLUOROMETHYLBENZE&;1-triethoxy(4-(trifluoromethyl)phenyl);triethoxy(4-(trifluoromethyl)phenyl)silane;1-TRIETHOXYSILYL-4-TRIFLUOROMETHYLBENZENE 97%
• CAS NO: 188748-63-2
• Molecular Formula: C₁₃H₁₉F₃O₃Si
• Molecular Weight: 308.37
• Product Categories: Organometallic Reagents;Organosilicon;Trialkoxysilanes
• Mol File: 188748-63-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 90-91 °C0.2 mm Hg(lit.)
• Flash Point: 230 °F
• Appearance: /
• Density: 1.098 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.222mmHg at 25°C
• Refractive Index: n20/D 1.436(lit.)
• CAS DataBase Reference: TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL&(CAS DataBase Reference)
• NIST Chemistry Reference: TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL&(188748-63-2)
• EPA Substance Registry System: TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL&(188748-63-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 188748-63-2(Hazardous Substances Data)

Usage

General Description

TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL is a chemical compound with the molecular formula C13H19F3O3Si. It is a silane compound that contains three ethoxy groups and a trifluoromethylphenyl group attached to a silicon atom. TRIETHOXY(4-(TRIFLUOROMETHYL)PHENYL)SIL& is commonly used as a coupling agent for the adhesion of organic polymer resins to inorganic materials. It can also be used as a surface modifier and adhesion promoter for various coatings, adhesives, and sealants. Additionally, it is used in the production of silicone polymers and in the synthesis of pharmaceuticals and agrochemicals. It has potential applications in the fields of materials science, industrial chemistry, and pharmaceutical research.

InChI:InChI=1/C13H19F3O3Si/c1-4-17-20(18-5-2,19-6-3)12-9-7-11(8-10-12)13(14,15)16/h7-10H,4-6H2,1-3H3

Upstream product

• 78-10-4 tetraethoxy orthosilicate 
• 402-43-7 p-trifluoromethylphenyl bromide 

Downstream Products

• 140483-60-9 4'-(trifluoromethyl)-[1,1'-biphenyl]-4-carbonitrile 
• 647842-34-0 ethyl 4'-(trifluoromethyl)-[1,1'-biphenyl]-4-carboxylate 
• 1099595-83-1 6-(4-trifluoromethylphenyl)quinoline 
• 1009026-35-0 phenyl[4'-(trifluoromethyl)[1,1'-biphenyl]-4-yl]methanone 
• 460743-71-9 2-(4-(trifluoro-methyl)phenyl)naphthalene 
• 142557-76-4 4-acetyl-4'-trifluoromethylbiphenyl 
• 1099595-82-0 4-trifluoromethyl-1-(3,4-methylenedioxyphenyl)lbenzene 
• 1203793-21-8 10-[4-(trifluoromethyl)phenyl]benzo[h]quinoline 
• 77918-46-8 diethyl (4-(trifluoromethyl)phenyl)-phosphonate 
• 728-86-9 phenyl[4-(trifluoromethyl)phenyl]methanone 
• 1582806-76-5 (S)-2-phthalimido-N-(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)-3-(4-(trifluoromethyl)phenyl)propanamide 
• 127783-73-7 methyl 4’-(trifluoromethyl)-[1,1’-biphenyl]-4-carboxylate 

Relevant articles and documents

Rhodium(III)-Catalyzed Direct C-H Arylation of Various Acyclic Enamides with Arylsilanes

The stereoselective β-C(sp2)-H arylation of various acyclic enamides with arylsilanes via Rh(III)-catalyzed cross-coupling reaction was illustrated. The methodology was characterized by extraordinary efficacy and stereoselectivity, a wide scope of substrates, good functional group tolerance, and the adoption of environmentally friendly arylsilanes. The utility of this present method was evidenced by the gram-scale synthesis and further elaboration of the product. In addition, Rh(III)-catalyzed C-H activation is considered to be the critical step in the reaction mechanism.

A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction

A series of aryltriethoxysilanes was synthesized from the reaction mixture of aryl bromide, Mg powder, 1,2-dibromoethane and tetraethyl orthosilicate in THF under ultrasound. This sonochemical Barbier-type reaction provides a simple and efficient method for preparation of aryltriethoxysilanes. The Hiyama cross-coupling reaction of phenyltriethoxysilane with bromobenzene was investigated under different palladium catalysts and Pd(PhCN)2Cl2 was found to be the best choice.