189031-60-5

Upstream product

• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 189031-59-2 N-tert-butoxylcarbonyl-N-(3-phenylprop-2-ynyl)-(4-toluene)sulfonamide 

Downstream Products

• 5848-57-7 N-<3-phenyl-2(Z)-propenyl>-4-methylphenylsulfonamide 
• 189031-62-7 Acetic acid (E)-4-[((Z)-3-phenyl-allyl)-(toluene-4-sulfonyl)-amino]-but-2-enyl ester 

Relevant academic research and scientific papers

On the faciality of intramolecular Palladium(0)-Catalysed 'metallo-ene-type' cyclisations

The palladium-calalysed 'metallo-ene' step in a cyclisation/β-elimination reaction sequence has been shown to be suprafacial with respect to the olefinic component. This reaction has been applied to the synthesis of a trisubstituted exocyclic alkenyl pyrrolidine with complete stereocontrol.