189031-63-8

Upstream product

• 189031-61-6 (N,N)-tert-butoxycarbonyl-cinnamyl-p-tosylamine 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 55613-61-1 (Z)-4-chlorobut-2-en-1-yl acetate 
• 5848-57-7 4-methyl-N-[(2E)-3-phenylprop-2-en-1-yl]benzene-1-sulfonamide 

Relevant academic research and scientific papers

On the faciality of intramolecular Palladium(0)-Catalysed 'metallo-ene-type' cyclisations

The palladium-calalysed 'metallo-ene' step in a cyclisation/β-elimination reaction sequence has been shown to be suprafacial with respect to the olefinic component. This reaction has been applied to the synthesis of a trisubstituted exocyclic alkenyl pyrrolidine with complete stereocontrol.