1891-14-1

Basic information

• Product Name: 4-Chloro-1,10-phenanthroline
• Synonyms: 4-Chloro-1,10-phenanthroline;4-Chloro-1,10-diazaphenanthrene
• CAS NO: 1891-14-1
• Molecular Formula: C₁₂H₇ClN₂
• Molecular Weight: 214.03
• Product Categories: Electronic Chemicals
• Mol File: 1891-14-1.mol
• Article Data: 3

Chemical Properties

• Melting Point: 180-230℃
• Boiling Point: 380.5 °C at 760 mmHg
• Flash Point: 215.8 °C
• Appearance: /
• Density: 1.375 g/cm³
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 4-Chloro-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chloro-1,10-phenanthroline(1891-14-1)
• EPA Substance Registry System: 4-Chloro-1,10-phenanthroline(1891-14-1)

Safety Data

• Hazardous Substances Data: 1891-14-1(Hazardous Substances Data)

Usage

General Description

4-Chloro-1,10-phenanthroline is a chemical compound that belongs to the phenanthroline family. It is a white to light yellow crystalline powder that is commonly used in chemical research and analysis as a chelating agent. 4-Chloro-1,10-phenanthroline is known for its ability to form stable complexes with metal ions, particularly transition metal ions such as copper, iron, and nickel. These complexes are often used in various fields, including analytical chemistry, biochemistry, and environmental science. Additionally, 4-Chloro-1,10-phenanthroline has been found to exhibit potential biological activities, making it a subject of interest in medicinal chemistry and pharmacology research.

Upstream product

• 23443-31-4 4-hydroxy-1,10-phenanthroline 
• 25063-76-7 2,2-Dimethyl-5-(quinolin-8-ylaminomethylene)-[1,3]dioxane-4,6-dione 
• 130728-49-3 diethyl [(quinolin-8-ylamino)methylene]malonate 
• 86443-19-8 ethyl 4-oxo-1,4-dihydro-1,10-phenanthroline-3-carboxylate 
• 53946-49-9 4-oxo-1,4-dihydro-[1,10]phenanthroline-3-carboxylic acid 
• 578-66-5 8-amino quinoline 
• 93533-15-4 1H-1,10-phenanthrolin-4-one 

Relevant articles and documents

New nonsymmetric phenanthrolines as very effective ligands in the palladium-catalyzed carbonylation of nitrobenzene

Inspired by the results of a previous mechanistic study, a series of mostly new nonsymmetric phenanthrolines were synthesized and tested as ligands in the palladium-catalyzed reductive carbonylation reaction of nitrobenzene to methyl phenylcarbamate. Very good results were obtained when the asymmetry was of an electronic nature (a donating substituent in the para position of one of the two pyridinic rings and an electron-withdrawing or no substituent on the para position of the other pyridinic ring), but steric hindrance in the ortho or meta position retarded the reaction. The TOF for the modified system is the highest ever reported for any carbonylation reaction of nitroarenes.

Luminescent Metal Complexes. Part 5. Luminescence Properties of Ring-substituted 1,10-Phenanthroline Tris-complexes of Ruthenium(II)

The absorption characteristics, emission spectra, luminescent quantum yields, and lifetimes are reported for 24 ruthenium(II) tris-1,10-phenanthroline complexes in EtOH-MeOH solution.Quantum yields fall between 0.019 and 0.403, the highest values being re