189222-52-4

Upstream product

• 92516-63-7 methyl 2,3,4-tri-O-benzoyl-6-O-p-toluenesulfonyl-β-D-galactopyranoside 
• 53182-61-9 methyl 2,3,4-tri-O-benzoyl-β-D-galactopyranoside 
• 53182-62-0 methyl-(O²,O³,O⁴-tribenzoyl-O⁶-trityl-β-D-galactopyranoside) 
• 98-88-4 benzoyl chloride 

Downstream Products

• 189222-56-8 methyl-(tri-O-benzoyl-6-deoxy-α-L-arabino-hex-5-enopyranoside) 
• 175436-19-8 methyl 2,3,4-tri-O-benzyl-6-deoxy-α-L-arabino-hex-5-enopyranoside 

Relevant academic research and scientific papers

Novel carbocyclic ring closure of hex-5-enopyranosides

Retention of configuration at the anomeric carbon atom is observed for a novel rearrangement of carbohydrates. The readily accessible vinyl acetal 1 undergoes a triisobutylaluminum-assisted, stereoselective transposition of an oxygen atom on the ring with