189264-45-7Relevant academic research and scientific papers
Desymmetrization of cyclohexadienones via bronsted acid-catalyzed enantioselective oxo-michael reaction
Gu, Qing,Rong, Zi-Qiang,Zheng, Chao,You, Shu-Li
supporting information; experimental part, p. 4056 - 4057 (2010/05/01)
Chemical Reaction Reprentation Desymmetrlzatlon of cyclohexadlenones via enantloselectlve oxo-Mlchael reaction catalyzed by chlral phosphoric add to afford highly enantloenrlched 1,4-dloxane and tetrahydrofuran derivatives In excellent yields has been realized. The newly established methodology allows the facile enantloselectlve synthesis of clerolndlclns C, D, and F.Copyright
Catalytic enantioselective silylation of acyclic and cyclic triols: Application to total syntheses of cleroindicins D, F, and C
You, Zhen,Hoveyda, Amir H.,Snapper, Marc L.
supporting information; experimental part, p. 547 - 550 (2009/04/14)
(Chemical Equation Presented) Pick one out of three: Acyclic and cyclic 1,2,3-triols are silylated with exceptional site- and enantioselectivity by a small-molecule catalyst to afford silyl ethers having a neighboring diol moiety. The new process is appli
Enantioselective total synthesis of all of the known chiral cleroindicins (C-F): Clarification among optical rotations and assignments
Wenderski, Todd A.,Huang, Shenlin,Pettus, Thomas R. R.
supporting information; experimental part, p. 4104 - 4109 (2009/09/25)
(Chemical Equation Presented) Enantioselective syntheses of all of the named chiral members of the cleroindicin family (C-F) are reported. This effort demonstrates the synthetic utility of a 2,4-dihydroxybenzaldehyde as a starting material for natural pro
