189264-47-9Relevant academic research and scientific papers
Catalytic enantioselective silylation of acyclic and cyclic triols: Application to total syntheses of cleroindicins D, F, and C
You, Zhen,Hoveyda, Amir H.,Snapper, Marc L.
supporting information; experimental part, p. 547 - 550 (2009/04/14)
(Chemical Equation Presented) Pick one out of three: Acyclic and cyclic 1,2,3-triols are silylated with exceptional site- and enantioselectivity by a small-molecule catalyst to afford silyl ethers having a neighboring diol moiety. The new process is appli
From p-benzoquinone to cyclohexane chirons: First asymmetric synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
Busque, Felix,Canto, Mariona,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia
, p. 2021 - 2032 (2007/10/03)
Starting from a common, easily available, enantiopure monoketal of p-benzoquinone, the synthesis of a large number of cyclohexane chirons has been achieved. The first synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide has been performed from one of these new building blocks. The wide variety of functional groups of this series of chirons makes them useful for subsequent synthetic processes.
First synthesis of (+)-rengyolone and (+)- and (-)-menisdaurilide
Canto, Mariona,De March, Pedro,Figueredo, Marta,Font, Josep,Rodriguez, Sonia,Alvarez-Larena, Angel,Piniella, Juan F.
, p. 455 - 459 (2007/10/03)
The benzofuranone natural products (+)-rengyolone and (+)- and (-)-menisdaurilide have been synthesised for the first time from a common enantiopure cyclohexane building block derived from a monoketal of p-benzoquinone.
