18930-06-8Relevant academic research and scientific papers
Contraction de cycle dans la substitution d'un triflate osidique
Grouiller, Annie
, p. 1709 - 1710 (2007/10/02)
Benzoate displacement of the 2-triflyl derivative of methyl 3-azido or 3-O-benzoyl-4-deoxy-α-DL-threo-pentopyranoside (1 or 4) occurs with a pyranose to furanose contraction reaction at C-2.This contraction is not observed with an azido displacement.
OUVERTURE D'EPOXYDES PAR DES ACIDES ORGANIQUES DANS L'H.M.P.T. : NOUVELLE VOIE D'ACCES A DES DESOXYPENTOPYRANOSIDES
Picq, D.,Anker, D.,Pacheco, H.
, p. 4517 - 4520 (2007/10/02)
The opening of pyranic epoxides with organic acids in HMPA leads to regioselectively esterified methyl deoxythreopentopyranosides ; one of them is a convenient intermediate to provide erythro isomers.
