189315-18-2Relevant academic research and scientific papers
Synthesis of galactofuranose-containing disaccharides using thioimidoyl-type donors
Euzen, Ronan,Ferrieres, Vincent,Plusquellec, Daniel
, p. 2759 - 2768 (2006)
Four galactofuranose-containing disaccharides have been prepared utilising various thioimidates [Galf-SC({double bond, long}NR)XR′] and suitably protected acceptors as key precursors. We observed that the efficiency of the coupling reactions was particula
A convenient synthesis of disaccharides containing furanoside units
Velty, Rachel,Benvegnu, Thierry,Gelin, Muriel,Privat, Eric,Plusquellec, Daniel
, p. 7 - 14 (2007/10/03)
Pent-4-enyl 2,3,5,6-tetra-O-acetyl-D-glycofuranosides were synthesized in a one-pot reaction by a ferric chloride-promoted glycosylation of 4-penten-1-ol with D-glucose, D-mannose, and D-galactose, respectively, in heterogeneous media, followed by in situ acetylation. These n-pentenyl glycosides are efficient glycofuranosyl donors and have therefore been used for the subsequent synthesis of various furanosyl-pyranoside type or furanosyl-furanoside type disaccharides related to archaebacterial glycolipids and protozoa glycoconjugates.
