189329-47-3

Basic information

• Product Name: (1R,5S,6S,7R)-7-Benzenesulfonyl-6-chloro-6-phenylsulfanyl-bicyclo[3.1.1]heptane
• Synonyms: (1R,5S,6S,7R)-7-Benzenesulfonyl-6-chloro-6-phenylsulfanyl-bicyclo[3.1.1]heptane
• CAS NO: 189329-47-3
• Molecular Weight: 378.944
• Mol File: 189329-47-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,5S,6S,7R)-7-Benzenesulfonyl-6-chloro-6-phenylsulfanyl-bicyclo[3.1.1]heptane(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,5S,6S,7R)-7-Benzenesulfonyl-6-chloro-6-phenylsulfanyl-bicyclo[3.1.1]heptane(189329-47-3)
• EPA Substance Registry System: (1R,5S,6S,7R)-7-Benzenesulfonyl-6-chloro-6-phenylsulfanyl-bicyclo[3.1.1]heptane(189329-47-3)

Safety Data

• Hazardous Substances Data: 189329-47-3(Hazardous Substances Data)

Upstream product

• 98-09-9 benzenesulfonyl chloride 
• 1212-08-4 S-Phenyl benzenethiosulfonate 

Downstream Products

• 189330-04-9 (1R,5S,6R,7S)-7-Benzenesulfonyl-6-methoxy-6-phenylsulfanyl-bicyclo[3.1.1]heptane 
• 189329-89-3 7-exo-(benzenesulfonyl)bicyclo[3.1.1]heptan-6-one 
• 189329-49-5 (1R,5S,6S,7R)-6,7-Bis-benzenesulfonyl-6-chloro-bicyclo[3.1.1]heptane 

Relevant articles and documents

Regio- and stereoselective addition of methane- and bromomethanesulfonyl bromides to 1-Phenylthiotricyclo[4.1.0.02,7]heptane

1-Phenylthiotricyclo[4.1.0.02,7]heptane reacted with MeSO 2Br and BrCH2SO2Br directly at mixing at 20°C in CH2Cl2 along a ionic (electrophilic with respect to bromine) mechanism affording a product of an anti-stereoselective addition to the central bicyclobutane C1-C7 bond of the norpinane structure. The reaction product contains the exo-oriented sulfonyl group in the geminal position to the SPh substituent. The structure of the adduct with MeSO2Br in a single crystal was determined by XRD analysis. Pleiades Publishing, Ltd., 2010.