18934-20-8

Usage

Uses

Used in Chemical Synthesis:
3,3'-((3-Methylphenyl)imino)bispropanenitrile is used as a building block for the synthesis of organic compounds, facilitating the creation of a wide range of chemical products due to its reactive nature and structural properties.
Used in Coordination Chemistry as a Ligand:
In the field of coordination chemistry, 3,3'-((3-Methylphenyl)imino)bispropanenitrile is utilized as a ligand to form coordination compounds with metal ions, which is crucial for various applications in material science and catalysis.
Used in Polymer Production:
3,3'-((3-Methylphenyl)imino)bispropanenitrile is employed in the production of polymers, where it contributes to the development of polymers with specific properties, such as stability and reactivity.
Used as a Stabilizer in Polymers:
In the polymer industry, 3,3'-((3-Methylphenyl)imino)bispropanenitrile is used as a stabilizer to enhance the performance and longevity of certain types of polymers, ensuring their stability under various conditions.
Used as an Intermediate in Pharmaceutical Synthesis:
3,3'-((3-Methylphenyl)imino)bispropanenitrile serves as an intermediate in the synthesis of pharmaceuticals, playing a crucial role in the development of new drugs and medicinal compounds.
Used as an Intermediate in Agrochemical Production:
Similarly, in the agrochemical industry, 3,3'-((3-Methylphenyl)imino)bispropanenitrile is used as an intermediate, contributing to the synthesis of various agrochemicals that are vital for agricultural applications.
Used in the Production of Other Industrial Chemicals:
3,3'-((3-Methylphenyl)imino)bispropanenitrile also finds use as a chemical intermediate in the production of other industrial chemicals, highlighting its importance in the broader chemical manufacturing sector.

Upstream product

• 107-13-1 acrylonitrile 
• 108-44-1 1-amino-3-methylbenzene 

Downstream Products

• 140636-30-2 3,9-Di-m-tolyl-1,2,3,4,5,7,8,9,10,11-decahydro-3,6,9,12-tetraaza-benzo[1,2;4,5]dicycloheptene 
• 947367-89-7 (2-methyl-4-(N,N-bis-(2'-cyanoethyl)amino)benzylidine)aniline 
• 947367-91-1 (2-methyl-4-(N,N-bis-(2'-cyanoethyl)amino)benzylidine)-p-chloroaniline 
• 947367-92-2 (2-methyl-4-(N,N-bis-(2'-cyanoethyl)amino)benzylidine)-p-toludine 
• 947367-90-0 (2-methyl-4-(N,N-bis-(2'-cyanoethyl)amino)benzylidine)-p-fluoroaniline 
• 20063-52-9 (2-methyl-4-N,N-bis-(2'-cyanoethyl)amino)benzaldehyde 

Relevant academic research and scientific papers

Synthesis and characterization of Schiff bases coordination compounds of lanthanide(III) perchlorates

Dicyanoethylation of m-toluidine was carried out by treating the aromatic primary amine with acryonitrile in acetic acid in presence of cuprous chloride. The cyanoethylated amine on formylation gave 2-methyl-4-NN-bis-2'- cyanoethylaminobenzaldehyde. The resulted aldehyde gave Schiff bases 2-methyl-4-NN-bis-2￠-cyanoethylaminobenzylidineaniline (MCEABAB), 2-methyl-4-NN-bis-2￠- cyanoethylaminobenzylidine p-chloroaniline (MCEABCAB), 2-methyl-4-NN-bis-2￠-cyanoethylaminobenzylidine p-toludine (MCEABPT) and 2-methyl-4-NN-bis-2￠-cyanoethylaminobenzylidine p-fluoroaniline (MCEABFAB) with aniline and three different substituted anilines. Lanthanide oxides viz., lanthanum oxide, praseodymium oxide and neodymium oxide were chosen to synthesize new complexes, heaving a general formula [Ln(L)6(ClO4)3] [where Ln = La, Pr and Nd; L = MCEABAB, MCEABCAB, MCEABPT and MCEABFAB]. In all twelve new lanthanide(III) perchlorate complexes of Schiff bases have been prepared. Elemental analyses, molecular weight, melting point, conductivity measurement, spectral studies, thermal analysis and microbial activities of the complexes were carried out.

Addition of amines and phenols to acrylonitrile derivatives catalyzed by the POCOP-type pincer complex [{κP,κC, κP-2,6-(i-Pr2PO)2C6H 3}Ni(NCMe)][OSO2CF3]

The pincer-type complex [{κP,κC, κP-2,6-(i-Pr2PO)2C6H 3}Ni(NCMe)][OSO2CF3] (1) can serve as a precatalyst for the regioselective, anti-Markovnikov addition of nucleophiles to activated olefins. The catalyzed additions of aliphatic amines to acrylonitrile, methacrylonitrile, and crotonitrile proceed at room temperature and give quantitative yields of products resulting from the formation of C-N bonds. On the other hand, aromatic amines or alcohols are completely inert toward methacrylonitrile and crotonitrile, and much less reactive toward acrylonitrile, requiring added base, heating, and extended reaction times to give good yields. The catalytic reactivities of 1 are thought to arise from the substitutional lability of the coordinated acetonitrile that allows competitive coordination of the nitrile moiety in the olefinic substrates; this binding enhances the electrophilicity of the CC moiety, rendering them more susceptible to attack by nucleophiles. In some cases, RCN → Ni binding results in double bond isomerization/migration (allyl cyanide) or attack of nucleophiles at the nitrile moiety (cinnamonitrile and 4-cyanostyrene). Reaction of morpholine with 1 at 60 °C led to formation of the amidine derivative 2 that has been characterized by X-ray crystallography.