189372-72-3

Basic information

• Product Name: Pt((η-CH2=CHSiMe2)2O)(PPh3)
• CAS NO: 189372-72-3
• Molecular Weight: 507.382
• Mol File: 189372-72-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pt((η-CH2=CHSiMe2)2O)(PPh3)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt((η-CH2=CHSiMe2)2O)(PPh3)(189372-72-3)
• EPA Substance Registry System: Pt((η-CH2=CHSiMe2)2O)(PPh3)(189372-72-3)

Safety Data

• Hazardous Substances Data: 189372-72-3(Hazardous Substances Data)

Upstream product

• 29046-78-4 (1,2-dimethoxyethane)dichloronickel(II) 
• 2627-95-4 tetramethyldivinyldisiloxane 
• 603-35-0 triphenylphosphine 
• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 
• 189372-83-6 tris(tetramethyldivinyldisiloxane)dinickel⁽⁰⁾ 

Relevant articles and documents

Simplified and versatile access to low valent Ni complexes by metal-free reduction of NiII precursors

The reduction of [Ni(DME)Cl2] with 2 equiv. of bis(trimethylsilyl)-1,4-tetramethyldihydropyrazine in the presence of a ligand L and an excess of olefin cleanly leads to [Ni(L)(alkene)2] complexes. When reduction is performed in the presence of 1,5-cyclooctadiene (COD), [Ni(COD)2] is obtained. Such an approach also allows access to the NiI dimer [Ni(bis(dicyclohexylphosphino)propane)Cl]2.