18938-05-1Relevant academic research and scientific papers
Formation of 2-cyclohexenones by Friedel-Crafts acylation of alkenes with β,γ-ethylenic acyl halides
Faure,Pommier,Pons,Rajzmann,Santelli
, p. 8419 - 8430 (2007/10/02)
Friedel-Crafts acylation of alkenes with β,γ-alkenoyl halides leads to conjugated Al-trienolates able to cyclize into Al-enolates of 2-cyclohexenones through an allowed thermal disrotary electrocyclization mechanism. Discussion of the product structures is based on two-dimensional NMR experiments (400 MHz) and molecular mechanics studies (GENMOL and MM2).
Synthetic Route to Tricyclic Carbon Compounds by Friedel-Crafts Acylation
Tubul, Arlette,Santelli, Maurice
, p. 191 - 192 (2007/10/02)
Acylation of cyclohexene by cyclohexenyl- or cyclopentenyl-acetyl chloride gave des-A-11-oxo or des-D-7-oxo steroids.
