18982-43-9Relevant academic research and scientific papers
Substrate promiscuity of ortho-naphthoquinone catalyst: Catalytic aerobic amine oxidation protocols to deaminative cross-coupling and n-nitrosation
Kim, Hun Young,Oh, Kyungsoo,Si, Tengda
, p. 9216 - 9221 (2019/10/08)
ortho-Naphthoquinone-based organocatalysts have been identified as versatile aerobic oxidation catalysts. Primary amines were readily cross-coupled with primary nitroalkanes via deaminative pathway to give nitroalkene derivatives in good to excellent yields. Secondary and tertiary amines were inert to ortho-naphthoquinone catalysts; however, secondary nitroalkanes were readily converted by ortho-naphthoquinone catalysts to the corresponding nitrite species that in situ oxidized the amines to the corresponding N-nitroso compounds. Without using harsh oxidants in a stoichiometric amount, the present catalytic aerobic oxidation protocol utilizes the substrate promiscuity feature to provide a facile access to amine oxidation products under mild reaction conditions.
Iron-catalyzed tandem one-pot addition and cyclization of the blaise reaction intermediate and nitroolefins: Synthesis of substituted NH-pyrroles from nitriles
Zhao, Mi-Na,Liang, Hao,Ren, Zhi-Hui,Guan, Zheng-Hui
supporting information, p. 221 - 226 (2013/03/13)
The iron-catalyzed addition and cyclization of the Blaise reaction intermediate and nitroolefins to synthesize highly functionalized NH-pyrroles in a tandem one-pot manner from nitriles has been developed. This reaction shows good functional group tolerance and affords a broad spectrum of substituted NH-pyrroles in good yields. Copyright
An efficient solventless synthesis of α-aryl-N-[1-methyl-2-(2/4- chlorophenyl)] ethyl nitrones and their antimicrobial activity
Amutha, Chinnadurai,Saravanan, Sivaperuman,Dhandapani, Perundurai Subramaniam,Muthusubramanian, Shanmugam,Sivasubramanian, Shanmugaperumal
, p. 276 - 282 (2008/09/20)
An efficient solventless synthesis of α-aryl-N-[1-methyl-2-(2/4- chlorophenyl)]ethyl nitrones has been achieved in excellent yield. The compounds are characterized by NMR and X-ray studies. The antimicrobial activities of the synthesized compounds have al
Porphyrin synthesis from nitrocompounds
Ono, Noboru,Kawamura, Hisayuki,Bougauchi, Masahiro,Maruyama, Kazuhiro
, p. 7483 - 7496 (2007/10/02)
A new porphyrin synthesis starting from nitroalkenes or their equivalents is described. For example, octaethylporphyrin, coproporphyrin, porphyrin-1,2,3,4,5,6,7,8 octapropionic acid, and 2,7,12,17 tetraarylporphyrin are prepared in good yield from readily available materials such as 1-nitropropane, nitroethane, nitromethane, and aldehydes.
