18988-74-4Relevant academic research and scientific papers
Icosahedral carboranes. XII. Direct fluorination of o-, m-, and p-carborane
Kongpricha, Santad,Schroeder, Hansjuergen
, p. 2449 - 2452 (1969)
Reaction of the parent carboranes with excess elemental fluorine in liquid hydrogen fluoride resulted in o-, m-, and p-B10F10C2H2 in yields of 30, 60, and 85%, respectively. Replacement of carbon-bonded hydrogen
A new series of organoboranes. II. The chlorination of 1,2-dicarbaclovododecaborane(12)
Schroeder, Hansjuergen,Heying, Theodore L.,Reiner, Joseph R.
, p. 1092 - 1096 (1963)
A detailed investigation of the chlorination of a new series of organoboranes derived from decaborane-14 resulted in the stepwise formation of a number of chlorocarboranes containing from two to eleven chlorine atoms per molecule. Some of their chemical characteristics are described; a detailed B11 n.m.r. treatment of the parent carborane (B10H10C2H2), B10Cl10-C2H2, and B10Cl10C2HCl as related to structural considerations is presented.
