18993-19-6Relevant academic research and scientific papers
Synthesis and characterization of 4'-amino and 4'-nitro derivatives of 4-N,N-dimethylaminotriphenylmethane as precursors for a proximate malachite green metabolite
Cho, Bongsup P,Blankenship, Lonnie R,Moody, Joanna D,Doerge, Daniel R,Beland, Frederick A,Culp, Sandra J
, p. 7379 - 7388 (2007/10/03)
This paper describes the preparation of 4'-amino (2) and 4'-nitro (3) derivatives of 4-N,N-dimethylaminotriphenylmethane as precursors for presumed DNA-binding metabolites of malachite green. The primary amine 2 was synthesized via a condensation of 4-lit
MECHANISM OF OXIDATION OF LEUCO BASES OF TRIARYLMETHANE DYES BY OXYGEN
Fedorova, T. M.,Kaliya, O. L.
, p. 1348 - 1352 (2007/10/02)
The kinetics of the oxidation of the leuco bases of triarylmethane dyes by oxygen were investigated.It was established that the oxidating agent was the peroxy radicals of the solvent.The leuco base is oxidized in the protonated form.A mechanism which involves the formation of a complex between the protonated leuco base and the peroxy radical is proposed.The decomposition of the complex in the controlling stage of the process leads to the formation of the dye.
