189950-31-0Relevant academic research and scientific papers
Dynamic Covalent Formation of Concave Disulfide Macrocycles Mechanically Interlocked with Single-Walled Carbon Nanotubes
Balakrishna, Bugga,Beil, Sebastian B.,Cao, Kecheng,Gs?nger, Sebastian,Guldi, Dirk M.,Hirsch, Andreas,Kaiser, Ute,Martin, Oliver,Menon, Arjun,Meyer, Bernd,Shyshov, Oleksandr,Villalva, Julia,von Delius, Max
, p. 18774 - 18785 (2020)
The formation of discrete macrocycles wrapped around single-walled carbon nanotubes (SWCNTs) has recently emerged as an appealing strategy to functionalize these carbon nanomaterials and modify their properties. Here, we demonstrate that the reversible di
ZnS Nanoparticles Sensitize Luminescence of Capping-Ligand-Bound Lanthanide Ions
Tigaa, Rodney A.,Lucas, Gary J.,De Bettencourt-Dias, Ana
, p. 3260 - 3268 (2017)
2,6-Bis(diethylamide)-4-oxo(3-thiopropane)pyridine (BDP) and 2,6-bis(methyl ester)-4-oxo(3-thiopropane)pyridine (BMP) were synthesized. These compounds chelated LnIII ions and sensitized their emission. The 3:1 complexes of BDP displayed effici
[2]Rotaxane End-Capping Synthesis by Click Michael-Type Addition to the Vinyl Sulfonyl Group
David, Arthur H. G.,García-Cerezo, Pablo,Campa?a, Araceli G.,Santoyo-González, Francisco,Blanco, Victor
, p. 6170 - 6179 (2019/04/08)
We report the application of the click Michael-type addition reaction to vinyl sulfone or vinyl sulfonate groups in the synthesis of rotaxanes through the threading-and-capping method. This methodology has proven to be efficient and versatile as it allowed the preparation of rotaxanes using template approaches based on different noncovalent interactions (i.e., donor-acceptor π–π interactions or hydrogen bonding) in yields of generally 60–80 % and up to 91 % aided by the mild conditions required (room temperature or 0 °C and a mild base such as Et3N or 4-(N,N-dimethylamino)pyridine (DMAP)). Furthermore, the use of vinyl sulfonate moieties, which are suitable motifs for coupling-and-decoupling (CAD) chemistry, implies another advantage because it allows the controlled chemical disassembly of the rotaxanes into their components through nucleophilic substitution of the sulfonates resulting from the capping step with a thiol under mild conditions (Cs2CO3 and room temperature).
Synthesis and Characterization of Two Tritylthio-Derivatives: 1-Bromo-3-Tritylthiopropane and 2-(Tritylthio)-Ethanethiol
Tigaa, Rodney A.,de Bettencourt-Dias, Ana
, p. 233 - 240 (2017/11/10)
Abstract: Two tritylthio-based compounds were synthesized: 1-bromo-3-tritylthiopropane 1 and 2-(tritylthio)-ethanethiol 2. They were characterized by infrared, NMR, UV–Vis absorption and fluorescence spectroscopy and single-crystal X-ray diffraction. The
NANOPARTICLES FOR DRUG DELIVERY
-
Page/Page column 55, (2016/04/20)
The invention provides therapeutic magnetic nanoparticles containing a therapeutic agent connected to a magnetic nanoparticle core through a stable functional group and a linker that can be induced to release the therapeutic agent from the core, through h
Synthesis of a toolbox of clickable rhodamine B derivatives
Gobbo, Pierangelo,Gunawardene, Praveen,Luo, Wilson,Workentin, Mark S.
supporting information, p. 1169 - 1174 (2015/03/31)
Abstract An efficient method for the large-scale preparation of rhodamine B clickable derivatives has been developed. Starting from inexpensive rhodamine B as the starting material it was possible to functionalize the carboxylic functionality of rhodamine B with an azide, a strained-alkyne, a substituted triphenylphosphine, a thiol, and a maleimide. Through the synthetic strategy it was possible to obtain stable and pure clickable rhodamine compounds that can be readily used not only for chemoselectively probing biomolecules, but also for materials science.
Synthesis of pyridine-based polyaminocarboxylic ligands bearing a thioalkyl anchor
Lin, Yi,Favre-Réguillon, Alain,Pellet-Rostaing, Stéphane,Lemaire, Marc
, p. 3463 - 3466 (2008/02/10)
A bicyclic tetraazatriacetic chelating agent containing a thioalkyl pendant group was prepared. Four synthetic routes have been investigated via a Mitsunobu reaction from 2,4-[bishydroxymethyl]-3-hydroxy-pyridine 1. Deprotection of trityl thioether compound 5c led to ligand 6c in 22% overall yield from the starting 3-hydroxypyridine.
