18998-17-9Relevant academic research and scientific papers
A catalytic approach to the metal-free reaction of epoxides with ketene silyl acetals for accessing γ-lactones
Bonollo, Simona,Ahmady, Amanollah Zarei,Petrucci, Chiara,Marrocchi, Assunta,Pizzo, Ferdinando,Vaccaro, Luigi
supporting information, p. 5721 - 5723 (2015/02/19)
The first catalytic approach to the nucleophilic addition of silyl ketene acetals 2 to epoxides 1 is reported. The defined protocol is metal-free using tetrabutylammonioum fluoride as the catalyst. It works in a very efficient manner under solvent-free co
Preparation of functionalized alkylmagnesium derivatives using an I/Mg-exchange
Rauhut, Christian B.,Vu, Viet Anh,Fleming, Fraser F.,Knochel, Paul
supporting information; experimental part, p. 1187 - 1189 (2009/04/06)
Functionalized alkylmagnesium reagents bearing an acetal, a ketal, an ester, or a pyridine ring were prepared by an I/Mg-exchange using iPr 2Mg-LiCI or CIMg(CH2)5MgCI-2LiCI starting from functionalized primary alkyl iodides.
